http://www.cnr.it/ontology/cnr/individuo/prodotto/ID233188
The interaction of molecular oxygen with aminophenols mediated by metal copper and copper compounds (Articolo in rivista)
- Type
- Label
- The interaction of molecular oxygen with aminophenols mediated by metal copper and copper compounds (Articolo in rivista) (literal)
- Anno
- 1992-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/0304-5102(92)80136-5 (literal)
- Alternative label
Prati L., Rossi M., Ravasio N. (1992)
The interaction of molecular oxygen with aminophenols mediated by metal copper and copper compounds
in Journal of molecular catalysis (Print); Elsevier Sequoia, Lausanne (Svizzera)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Prati L., Rossi M., Ravasio N. (literal)
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- ISI Web of Science (WOS) (literal)
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- Università di Bari e CNR Centro MISO, via Amendola 173, 70126 Bari
Università di Milano e CNR Centro CSMTBO, via Venezian 21, 20133 Milano (literal)
- Titolo
- The interaction of molecular oxygen with aminophenols mediated by metal copper and copper compounds (literal)
- Abstract
- Several copper compounds (Cu, Cu2O, CuO, CuCl and CuCl2) have been used as catalysts for the oxidation of 2-, 3- and 4-aminophenol with O2 at 25 °C; a comparison of their activities was made through kinetic determinations. The oxidation of 2-aminophenol selectively produced 2-amino-phenoxazin-3-one (1), whereas the oxidation products of 3- and 4-aminophenol were two new compounds, 2-amino-5 [(3-hydroxyphenyl) amino]-2,5-cyclohexadiene-1,4-dione (3) and 3-[(4-hydroxyphenyl)amino]-4-[(2-amino-5-hydroxy) phenyl]-6-[(4-hydroxyphenyl)imino]-2,4-cyclohexadien-1-one (2) (literal)
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