CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/c3ob40264a (literal)

Alternative label

• Fraile, Jose M.; Le Jeune, Karel; Mayoral, Jose A.; Ravasio, Nicoletta; Zaccheria, Federica (2013)
  CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds
  in Organic & biomolecular chemistry; Royal Society of Chemistry, Cambridge (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Fraile, Jose M.; Le Jeune, Karel; Mayoral, Jose A.; Ravasio, Nicoletta; Zaccheria, Federica (literal)

Pagina inizio

• 4327 (literal)

Pagina fine

• 4332 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Inside front cover del fascicolo (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 11 (literal)

Rivista

• Organic & biomolecular chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 26 (literal)

Note

• Scopus (literal)
• SCImago (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ISQCH - Instituto de Sintesis Quimica y Catalisis Homogenea, Universidad de Zaragoza-CSIC, C/ Pedro Cerbuna, 12 E-50009 Zaragoza, Spain (literal)

Titolo

• CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds (literal)

Abstract

• The purely inorganic copper oxide on silica catalyzes the reaction of methyl phenyldiazoacetate with N-methyl indole under mild reaction conditions, giving the alkylation (formally a C-H insertion) in position 3, and the catalyst can be recovered and reused at least in 5 consecutive runs with only minor loss in activity. The scope of the reaction includes various diazo compounds and indole or pyrrole derivatives leading to alkylation or cyclopropanation depending on the heterocycle structure. An alternative mechanism, without reduction of Cu(II) to Cu(I), is proposed on the basis of the obtained results. (literal)

Editore

• Royal Society of Chemistry (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR

• FEDERICA ZACCHERIA (Unità di personale interno)
• MARIA NICOLETTA RAVASIO (Persona)

Insieme di parole chiave

• Parole chiave di "CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR di

• FEDERICA ZACCHERIA (Unità di personale interno)
• MARIA NICOLETTA RAVASIO (Persona)

Editore di

• Royal Society of Chemistry (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organic & biomolecular chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds" (Insieme di parole chiave)