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Inverse freezing in molecular binary mixtures of alpha-cyclodextrin and 4-methylpyridine (Articolo in rivista)

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Inverse freezing in molecular binary mixtures of alpha-cyclodextrin and 4-methylpyridine (Articolo in rivista) (literal)

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Alternative label

Plazanet, M; Bartolini, P; Sangregorio, C; Taschin, A; Torre, R; Trommsdorff, HP (2010)
Inverse freezing in molecular binary mixtures of alpha-cyclodextrin and 4-methylpyridine
in PCCP. Physical chemistry chemical physics (Print); ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE,, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND (Regno Unito)
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Plazanet, M; Bartolini, P; Sangregorio, C; Taschin, A; Torre, R; Trommsdorff, HP (literal)

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1 ] Univ Florence, European Lab Nonlinear Spect LENS, I-50019 Florence, Italy 2 ] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France 3 ] Univ Grenoble 1, CNRS, UMR 5588, Spectrometrie Phys Lab, F-38402 St Martin Dheres Cx, France 4 ] Univ Florence, Dipartimento Chim, I-50019 Florence, Italy 5 ] Univ Florence, INSTM, I-50019 Florence, Italy 6 ] Univ Florence, Dipartimento Fis, I-50019 Florence, Italy (literal)

Titolo

Inverse freezing in molecular binary mixtures of alpha-cyclodextrin and 4-methylpyridine (literal)

Abstract

Ternary solutions of alpha-cyclodextrin (alpha CD) in 4-methylpyridine (4MP)/water mixtures solidify when heated and melt when cooled, and the crystalline solid phase exhibits a rich phase behavior as a function of temperature. In this work, we extend these earlier investigations to pure binary mixtures of alpha CD in water free 4MP, characterized via temperature and time dependent measurements of viscosity, X-ray diffraction, and infrared spectroscopy, complemented by observations of acoustic properties and small angle neutron diffraction. At high concentrations (>500 g l(-1)), these solutions enter an amorphous solid phase not only with decreasing but also with increasing temperature, before crystallizing at higher temperatures. This inverse solidi. cation is attributed to the growth of hydrogen bonded clusters, leading to a steep increase of the viscosity with temperature. (literal)

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