Synthesis of the first chiral phosphorous chelate aminophosphino-carbene complex and its applications in stereoselective addition reactions (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Synthesis of the first chiral phosphorous chelate aminophosphino-carbene complex and its applications in stereoselective addition reactions (Articolo in rivista) (literal)

Anno

• 1999-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/S0020-1693(99)00372-2 (literal)

Alternative label

• S. Maiorana, A. Papagni, E. Licandro, D. Perdicchia, C. Baldoli, C. Graiff, A. Tiripicchio. (1999)
  Synthesis of the first chiral phosphorous chelate aminophosphino-carbene complex and its applications in stereoselective addition reactions
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• S. Maiorana, A. Papagni, E. Licandro, D. Perdicchia, C. Baldoli, C. Graiff, A. Tiripicchio. (literal)

Pagina inizio

• 236 (literal)

Pagina fine

• 245 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 296 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• Scopus (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università degli Studi di Milano; CNR-Istituto di Scienze e Tecnologie Molecolari; Università degliStudi di Parma (literal)

Titolo

• Synthesis of the first chiral phosphorous chelate aminophosphino-carbene complex and its applications in stereoselective addition reactions (literal)

Abstract

• The first phosphorous chelate chiral aminophosphinomethyl carbene complex [cyclic] (OC)4Cr:C(Me)N(Me)CH2CH(Ph)PPh2 5 was synthesized. Its conjugate base represents a new chiral ?-unsubstituted amide enolate equiv. for stereoselective addn. reactions. The structure of the major diastereoisomer of the aldol addn. complex between 5 and p-O2NC6H4CHO, solved by x-ray diffraction, shows that the (S)-enantiomer of the conjugated base of 5 reacts preferentially with the re face of the carbonyl function (literal)

Prodotto di

• Institute of molecular science and technologies (ISTM) (Istituto)

Autore CNR

• CLARA BALDOLI (Unità di personale interno)

Incoming links:

Prodotto

• Institute of molecular science and technologies (ISTM) (Istituto)

Autore CNR di

• CLARA BALDOLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)