Studies of the stereoselective allylation of chiral benzaldimine chromium tricarbonyl complexes (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Studies of the stereoselective allylation of chiral benzaldimine chromium tricarbonyl complexes (Articolo in rivista) (literal)

Anno

• 2000-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/S0022-328X(99)00601-4 (literal)

Alternative label

• Maiorana, Stefano; Baldoli, Clara; Del Buttero, Paola; Licandro, Emanuela; Papagni, Antonio; Lanfranchi, Maurizio; Tiripicchio, Antonio (2000)
  Studies of the stereoselective allylation of chiral benzaldimine chromium tricarbonyl complexes
  in Journal of organometallic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Maiorana, Stefano; Baldoli, Clara; Del Buttero, Paola; Licandro, Emanuela; Papagni, Antonio; Lanfranchi, Maurizio; Tiripicchio, Antonio (literal)

Pagina inizio

• 380 (literal)

Pagina fine

• 387 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 593-594 (literal)

Rivista

• Journal of organometallic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università degli Studi di Milano; CNR-Istituto di Scienze e Tecnologie Molecolari (literal)

Titolo

• Studies of the stereoselective allylation of chiral benzaldimine chromium tricarbonyl complexes (literal)

Abstract

• Highly stereoselective allylation of a series of chiral tricarbonylchromium benzaldimine complexes was achieved at -20° and homoallyl amine complexes, e.g. I, were isolated in good yields. In the case of homoallyl amine I, obtained in 75% d.e., the degree of stereoselection depends on the catalyst and the reaction conditions. The crystal structure of the major diastereoisomer of racemic I was detd. by x-ray diffraction, which showed a (S,S) or (R,R) configuration, in agreement with the stereochem. model operating for the ortho-substituted tricarbonylchromium arene complexes. Furthermore, the new tricarbonylchromium complex of N-(2-methoxybenzylidene)diphenyl phosphinamide was prepd. This substrate is a stable analog of the normally un-viable ammonia imine (literal)

Prodotto di

• Institute of molecular science and technologies (ISTM) (Istituto)

Autore CNR

• CLARA BALDOLI (Unità di personale interno)

Incoming links:

Prodotto

• Institute of molecular science and technologies (ISTM) (Istituto)

Autore CNR di

• CLARA BALDOLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of organometallic chemistry (Rivista)