Mixed tri- and bi-dentate Schiff-base complexes of technetium(V) and rhenium(V). The crystal structure of N-(2-oxidophenyl)salicylideneiminato-NOO?)oxo(8-quinolinolato-NO) technetium(V) (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Mixed tri- and bi-dentate Schiff-base complexes of technetium(V) and rhenium(V). The crystal structure of N-(2-oxidophenyl)salicylideneiminato-NOO?)oxo(8-quinolinolato-NO) technetium(V) (Articolo in rivista) (literal)

Anno

• 1986-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/DT9860001623 (literal)

Alternative label

• Mazzi U.; Refosco F.; Tisato F.; Bandoli G.; Nicolini M. (1986)
  Mixed tri- and bi-dentate Schiff-base complexes of technetium(V) and rhenium(V). The crystal structure of N-(2-oxidophenyl)salicylideneiminato-NOO?)oxo(8-quinolinolato-NO) technetium(V)
  in Journal of the Chemical Society. Dalton Transactions (2001)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Mazzi U.; Refosco F.; Tisato F.; Bandoli G.; Nicolini M. (literal)

Pagina inizio

• 1623 (literal)

Pagina fine

• 1628 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/Content/ArticleLanding/1986/DT/dt9860001623 (literal)

Rivista

• Journal of the Chemical Society. Dalton Transactions (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8 (literal)

Note

• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-3 : Istituto di Chimica e Tecnologia dei Radioelementi del CNR, Corso Stati Uniti 4, 35020 Padova, Italy / 4,5 : Dipartimento di Scienze Farmaceutiche, Università di Padova, Via Marzolo 5, 35131 Padova, Italy (literal)

Titolo

• Mixed tri- and bi-dentate Schiff-base complexes of technetium(V) and rhenium(V). The crystal structure of N-(2-oxidophenyl)salicylideneiminato-NOO?)oxo(8-quinolinolato-NO) technetium(V) (literal)

Abstract

• Six-co-ordinate complexes of technetium(V) and rhenium(V) containing the MO3+ core with triand bi-dentate Schiff-base ligands were synthesized and characterized. The complexes with general formula [MO(L1)L] [M = Tc or Re; L1 = N-(2-oxidophenyl)salicylideneiminate; L = salicylideneiminate, N-methyl- and N-phenyl-salicylideneiminate, or 8-quinolinolato (quin)] were characterized by elemental analysis, i.r.,1H n.m.r., and mass spectroscopy. The structure of [TcO(L1)(quin)] was also determined by X-ray analysis. The co-ordination around the metal is approximately octahedral. The phenolic oxygen of the quip ligand is trans to the Tc=O group. The tridentate Schiff-base ligand lies on the equatorial plane with respect to Tc=O. The complex crystallizes in monoclinic space group P21/n with a = 15.496(8), b = 10.355(4), c = 12.122(5) Å, ? = 109.03(6)°, and Z = 4. The structure has been refined to R = 0.054 for 2 025 observed reflections. (literal)

Prodotto di

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• FIORENZO REFOSCO (Unità di personale interno)
• FRANCESCO TISATO (Persona)

Incoming links:

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR di

• FRANCESCO TISATO (Persona)
• FIORENZO REFOSCO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of the Chemical Society. Dalton Transactions (Rivista)