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Functional properties of BaTiO3-Ni0.5Zn0.5Fe2O4 magnetoelectric ceramics prepared from powders with core-shell structure (Articolo in rivista)
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- Functional properties of BaTiO3-Ni0.5Zn0.5Fe2O4 magnetoelectric ceramics prepared from powders with core-shell structure (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1063/1.3340844 (literal)
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L. Curecheriu; M. T. Buscaglia; V. Buscaglia; L. Mitoseriu; P. Postolache; A. Ianculescu; P. Nanni (2010)
Functional properties of BaTiO3-Ni0.5Zn0.5Fe2O4 magnetoelectric ceramics prepared from powders with core-shell structure
in Journal of applied physics (online); American Institute of Physics, Melville [NY] (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- L. Curecheriu; M. T. Buscaglia; V. Buscaglia; L. Mitoseriu; P. Postolache; A. Ianculescu; P. Nanni (literal)
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- http://puma.isti.cnr.it/linkres.php?resource=cnr.ieni/cnr.ieni.ge/2010-A0-032 (literal)
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- In: Journal of Applied Physics, vol. 107 (10) article n. 104106. American Institute of Physics, 2010. (literal)
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- Department of Physics, Al. I. Cuza University, Bv. Carol I, no. 11, Iasi 700506, Romania; CNR-IENI, Genova; Department of Oxide Materials Science and Engineering, Polytechnics University, 1-7 Gh. Polizu, P.O. Box 12-134, Bucharest 011061, Romania; Department of Chemistry and Process Engineering, University of Genoa, P-le Kennedy no. 1, Genoa, Italy (literal)
- Titolo
- Functional properties of BaTiO3-Ni0.5Zn0.5Fe2O4 magnetoelectric ceramics prepared from powders with core-shell structure (literal)
- Abstract
- In the present work, diphasic ceramic composites with core-shell nanostructures formed by
Ni0.50Zn0.50Fe2O4 core and BaTiO3 shell were investigated. Their properties were compared with
those of composites prepared by coprecipitation. The core-shell structure was confirmed by
microstructural powder analysis. Homogeneous microstructures with a good phase mixing and
percolated dielectric phase by the magnetic one were obtained from coprecipitated powders. Less
homogeneous microstructures resulted in ceramics produced from the powder prepared by
core-shell method, with isolated small ferrite grains besides large ferrite aggregates embedded into
the BaTiO3 matrix. Both the ferroelectric and magnetic phases preserve their basic properties in bulk
composite form. However, important differences in the dielectric relaxation and conduction
mechanisms were found as result of the microstructural difference. Extrinsic contributions play
important roles in modifying the electric properties in both ceramics, causing space charge effect,
Maxwell-Wagner relaxations and hopping conductivity, mainly due to the ferrite low resistivity
phase. The conductivity and dielectric modulus spectra analysis allowed to identify different polaron
contributions associated with the microstructural differences. It results that by using the core-shell
method, improved dielectric properties and limited hopping contributions can be realized. (literal)
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