Synthesis of triscyclopentadienyl(triphenylgermyl)uranium and facile isonitrile insertion into the uranium-germanium bond (Articolo in rivista)

Type
Label
  • Synthesis of triscyclopentadienyl(triphenylgermyl)uranium and facile isonitrile insertion into the uranium-germanium bond (Articolo in rivista) (literal)
Anno
  • 1987-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/C39870000550 (literal)
Alternative label
  • Porchia M.; Ossola F.; Rossetto G.; Zanella P.; Brianese N. (1987)
    Synthesis of triscyclopentadienyl(triphenylgermyl)uranium and facile isonitrile insertion into the uranium-germanium bond
    in Journal of the Chemical Society. Chemical communications
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Porchia M.; Ossola F.; Rossetto G.; Zanella P.; Brianese N. (literal)
Pagina inizio
  • 550 (literal)
Pagina fine
  • 551 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.rsc.org/en/content/articlepdf/1987/c3/c39870000550 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 8 (literal)
Note
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Chimica e Tecnologia dei Radioelementi del C.N.R., Corso Stati Uniti, 35100 Padova, Italy (literal)
Titolo
  • Synthesis of triscyclopentadienyl(triphenylgermyl)uranium and facile isonitrile insertion into the uranium-germanium bond (literal)
Abstract
  • The uranium-germanium bonded complex (cp)3UGePh3 (1) (cp = ?5-C5H5) has been prepared from (cp)3UCl and KGePh3 and fully characterized; it reacts readily with 2,6-dimethylphenyl isocyanide [(Xyl)NC] to give the carbamoyl insertion product (cp)3U[C(GePh3)=N(Xyl)] (2), the dynamic 1H n.m.r. behaviour of which is described. (literal)
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