Insertion of 2,6-dimethylphenyl isocyanide into the U-N bond of [U(?-C5H5)3(NEt2)]. Crystal structure of [U(?-C5H5)3{C(NEt2)=NC 6H3Me2-2,6}] (Articolo in rivista)

Type
Label
  • Insertion of 2,6-dimethylphenyl isocyanide into the U-N bond of [U(?-C5H5)3(NEt2)]. Crystal structure of [U(?-C5H5)3{C(NEt2)=NC 6H3Me2-2,6}] (Articolo in rivista) (literal)
Anno
  • 1987-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/DT9870002039 (literal)
Alternative label
  • Zanella P.; Brianese N.; Casellato U.; Ossola F.; Porchia M.; Rossetto G.; Graziani R. (1987)
    Insertion of 2,6-dimethylphenyl isocyanide into the U-N bond of [U(?-C5H5)3(NEt2)]. Crystal structure of [U(?-C5H5)3{C(NEt2)=NC 6H3Me2-2,6}]
    in Journal of the Chemical Society. Dalton Transactions (2001)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Zanella P.; Brianese N.; Casellato U.; Ossola F.; Porchia M.; Rossetto G.; Graziani R. (literal)
Pagina fine
  • 2039 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.rsc.org/en/Content/ArticleLanding/1987/DT/dt9870002039 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 2043 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 8 (literal)
Note
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1-6 : lstituto di Chimica e Tecnologia dei Radioelementi C.N.R., Corso Stati Uniti, 35700 Padova, Italy 7 : Dipartimento di Chimica lnorganica Metallorganica ed Analitica, Universita di Padova, Via L oredan 4, 35100 Padova, Italy (literal)
Titolo
  • Insertion of 2,6-dimethylphenyl isocyanide into the U-N bond of [U(?-C5H5)3(NEt2)]. Crystal structure of [U(?-C5H5)3{C(NEt2)=NC 6H3Me2-2,6}] (literal)
Abstract
  • Insertion of CNC6H3Me2-2,6 into the U-N bonds of [U(?-C5H5)2(NEt2)2] and [U(?-C5H5)3(NEt2)] has been observed, leading to the formation of iminocarbamoyl derivatives. The structure of one of the resulting complexes [U(?-C5H5)3{C(NEt2)=NC 6H3Me2-2,6}] has been determined by X-ray analysis; this shows that the [C(NEt2)=NC6H3Me2-2,6]- anion is ?2-co-ordinated and the C=N double bond lies perpendicular to the U-M axis (where M is the midpoint of the C=N bond). 1H N.m.r. shows that the C5H5 protons are magnetically inequivalent. Some evidence of the insertion of CNC6H3Me2-2,6 into the U-P bond of [U(?-C5H5)3(PPh2)] is also reported. (literal)
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