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Synthesis and characterization of hexakis(diethylamido)diindium(III) and bis-cyclopentadienyl(diethylamido)indium(III) (Articolo in rivista)

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Synthesis and characterization of hexakis(diethylamido)diindium(III) and bis-cyclopentadienyl(diethylamido)indium(III) (Articolo in rivista) (literal)

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G. Rossetto; N. Brianese; A. Camporese; M. Porchia; R. Bertoncello (1991)
Synthesis and characterization of hexakis(diethylamido)diindium(III) and bis-cyclopentadienyl(diethylamido)indium(III)
in Main group metal chemistry
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1-4 Istituto di Chimica e Tecnologia dei Radioelementi, CNR - Corso Stati Uniti 4, I-35100 Padova, Italy 5 Dipartimento di Chimica Inorganica, Metallorganica ed Analitica, Università di Padova, I-35100 Padova, Italy (literal)

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Synthesis and characterization of hexakis(diethylamido)diindium(III) and bis-cyclopentadienyl(diethylamido)indium(III) (literal)

Abstract

[In(NEt2)3]2 has been synthesized by reaction of anhydrous InCl3 with LiNEt2 in diethyl ether solution. Reaction of the new product with a moderately acidic agent such as CpH leads to the cleavage of the In-NEt2 bonds with formation of Cp2InNEt2, whereas reactions at high temperature (400°C) with Ph2PH or PhPH2 give a mixture of products whose analysis by XPS indicates the presence of InP and carbon. The new indiumamides have been spectroscopically characterized by ir and 1H and 13C nmr. (literal)

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