http://www.cnr.it/ontology/cnr/individuo/prodotto/ID22131
Structural coherence and ferroelectricity decay in submicron- and nano-sized perovskites (Articolo in rivista)
- Type
- Label
- Structural coherence and ferroelectricity decay in submicron- and nano-sized perovskites (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.78.054107 (literal)
- Alternative label
V. Petkov; V. Buscaglia; M. T. Buscaglia; Z. Zhao; Y. Ren (2008)
Structural coherence and ferroelectricity decay in submicron- and nano-sized perovskites
in Physical review. B, Condensed matter and materials physics; American Physical Society (APS), College Pk (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- V. Petkov; V. Buscaglia; M. T. Buscaglia; Z. Zhao; Y. Ren (literal)
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- http://puma.isti.cnr.it/linkres.php?resource=cnr.ieni/cnr.ieni.ge/2008-A0-015 (literal)
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- Department of Physics, Central Michigan University, Mount Pleasant, Michigan 48859, USA; Institute for Energetics and Interphases, CNR, Via De Marini 6, I-16149 Genoa, Italy; Institute of Inorganic Chemistry, University of Stockholm, S10691 Stockholm, Sweden; Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA (literal)
- Titolo
- Structural coherence and ferroelectricity decay in submicron- and nano-sized perovskites (literal)
- Abstract
- Understanding the loss of ferroelectricity in submicron- and nano-sized perovskites is an issue that has been debated for decades. Here we report results from a high-energy x-ray diffraction (XRD) study on a prime
example of the perovskites family, BaTiO3 ceramics with a grain size ranging from 1200 to 5 nm. We find that the loss of ferroelectricity in submicron- and nano-sized BaTiO3 has an intrinsic origin related to the increased atomic positional disorder in spatially confined physical systems. Our results imply that no particular critical
size at which ferroelectricity in BaTiO3, in particular, and perovskites, in general, is completely lost exists. Rather it weakens exponentially with the decreasing of their physical size. Smart technological solutions are needed to bring it back. (literal)
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