Diethylindium(III) derivatives: Synthesis and characterization of diethylindium(III) dialkylamides and diethylindium(III) pyrrolide. X-Ray crystal structures of diethylindium(III) pyrrolide and diethylindium(III) bromide (Articolo in rivista)

Type
Label
  • Diethylindium(III) derivatives: Synthesis and characterization of diethylindium(III) dialkylamides and diethylindium(III) pyrrolide. X-Ray crystal structures of diethylindium(III) pyrrolide and diethylindium(III) bromide (Articolo in rivista) (literal)
Anno
  • 1992-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/0022-328X(92)85001-D (literal)
Alternative label
  • Porchia M.; Benetollo F.; Brianese N.; Rossetto G.; Zanella P.; Bombieri G. (1992)
    Diethylindium(III) derivatives: Synthesis and characterization of diethylindium(III) dialkylamides and diethylindium(III) pyrrolide. X-Ray crystal structures of diethylindium(III) pyrrolide and diethylindium(III) bromide
    in Journal of organometallic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Porchia M.; Benetollo F.; Brianese N.; Rossetto G.; Zanella P.; Bombieri G. (literal)
Pagina inizio
  • 1 (literal)
Pagina fine
  • 13 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://ac.els-cdn.com/0022328X9285001D/1-s2.0-0022328X9285001D-main.pdf?_tid=332f7804-c9eb-11e2-9310-00000aab0f02&acdnat=1370002459_a90f395cb158198cbed24c8b8c828506 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 424 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 14 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
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  • 1-5 : CNR-Istituto di Chimica e Tecnologia dei Radioelementi, Corso Stati Uniti, 35100 Padua, Italy/ 6 : Università di Milano-Istituto di Chimica Farmaceutica e Tossicologica, Viale Abruzzi 42, 20100 Milano, Italy (literal)
Titolo
  • Diethylindium(III) derivatives: Synthesis and characterization of diethylindium(III) dialkylamides and diethylindium(III) pyrrolide. X-Ray crystal structures of diethylindium(III) pyrrolide and diethylindium(III) bromide (literal)
Abstract
  • The compounds Et2InNR2 (R Me, Et, or SiMe3) and Et2InPyrr (HPyrr pyrrole) have been prepared by reaction of Et2InCl with the corresponding lithium amide or pyrrolide in diethylether. Their 1H NMR, IR and mass spectra are reported and discussed. The amides are dimers in the vapour phase. Diethylindium bromide is a layer polymer. The octahedral coordination geometry of indium is characterized by four distinct InBr distances ranging from 2.777(2) to 3.848(2) Å. Diethylindium pyrrolide has a chain structure as shown by the relatively short intermolecular interactions between each indium atom and the double bonds of two adjacent different pyrrole units (3.063(5) and 2.950(5) Å, respectively). The indium coordination geometry is then trigonal bipyramidal, with the shortest bonds in the equatorial plane (InC(5) 2.143(5) Å, InC(7) 2.141(5) Å, InN 2.166(4) Å). (literal)
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