Development of a passive sampling technique for the determination of nitrogen dioxide and sulphur dioxide in ambient air (Articolo in rivista)

Type
Label
  • Development of a passive sampling technique for the determination of nitrogen dioxide and sulphur dioxide in ambient air (Articolo in rivista) (literal)
Anno
  • 1997-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/S0003-2670(97)00075-5 (literal)
Alternative label
  • "De Santis Franco", "Allegrini Ivo", "Fazio Maria Cristina", "Pasella Daniela", "Piredda Roberta" (coautore alla pari) (1997)
    Development of a passive sampling technique for the determination of nitrogen dioxide and sulphur dioxide in ambient air
    in Analytica chimica acta (Print); Elsevier Science Publishers B.V., North Holland (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • \"De Santis Franco\", \"Allegrini Ivo\", \"Fazio Maria Cristina\", \"Pasella Daniela\", \"Piredda Roberta\" (coautore alla pari) (literal)
Pagina inizio
  • 127 (literal)
Pagina fine
  • 134 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • numero di citazioni alla data della domanda: 28 Impact factor della rivista alla data di pubblicazione del prodotto (1997): 1.778 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 346 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 8 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 1 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto sull'inquinamento atmosferico Consiglio Nazionale delle Ricerche Via Salaria Km. 29.300 Roma (literal)
Titolo
  • Development of a passive sampling technique for the determination of nitrogen dioxide and sulphur dioxide in ambient air (literal)
Abstract
  • Since conventional badge-type samplers depend entirely on an empirical calibration against gas mixtures and use of the constant determined for calculations, a system based on the use of two badge-type passive samplers of different lengths has been studied for the determination of NO2 or SO2. The samplers make use of a filter membrane barrier to damp out eddy motions and promote molecular diffusion from the ambient air to the trapping medium. The badges have a large ratio of crosssectional area to length of diffusion in order to increase sensitivity. Diffusion theory applied to this configuration shows that the concentration results are indipendent from wind-flow velocity. The samplers have been evaluated at different levels of relative humidity ranging from 0% to 90%. Batches of samplers were exposed for 48 h side-by-side with samplers exposed or consecutive periods of 24 h over the same interval. The results, expressed as a ratio (R=0.98±0.05 for nitrite and R=1,08±0,09 for sulphate). The detection limit attained (5ppb of NO2 and 10 ppb of SO2 for a 24h sampling) is adeguate for the determination in urban and rural areas. The accuracy of the proposed method, expressed as percent relative error, when compared to a standard denudar technique for NO2 and SO2, was found to be better than about ±10% with coefficient of variation of 5.5% and 6.5%, respectively. (literal)
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