Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2 (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2 (Articolo in rivista) (literal)

Anno

• 1994-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/om00022a055 (literal)

Alternative label

• Casellato U.; Ossola F. (1994)
  Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Casellato U.; Ossola F. (literal)

Pagina inizio

• 4105 (literal)

Pagina fine

• 4108 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/om00022a055 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 13 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 10 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica e Tecnologie Inorganiche e dei Materiali Avanzati, Area della Ricerca del CNR, Corso Stati Uniti 4, 1-35127 Padova, Italy (literal)

Titolo

• Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2 (literal)

Abstract

• CrCl3·3THF reacts with [(Me2NCH2CH2-CH2)Mg 2Cl3(THF)2]2 (1) in THF at room temperature to form the complex [{(Me2NCH2CH2CH2) 2Cr(?Cl)2}2Mg] (2). The solid-state structures of 1 and 2 have been determined by X-ray crystal analysis. 1 is triclinic, space group P1 (No. 2), with a = 10.035(8) Å, b = 10.393(8) Å, c = 10.707(8) Å, ? = 75.59(6)°, ? = 68.61(6)°, ? = 75.28-(7)°, and Z = 1 (the asymmetric unit is half of the molecule); the structure was refined to a conventional R factor of 0.079. In this tetranuclear Grignard reagent 1 Mg and Cl atoms form a system of five four-membered bridging units, where the Mg atoms exhibit five and six coordination and are connected by doubly (?) or triply (?3) bridging chloro ligands. 2 is triclinic, space group P1 (No. 2), with a = 8.514(8) Å, b = 12.471(9) Å, c = 14.976(9) Å, ? = 81.54(5)°, ? = 92.52(6)°, ? = 95.32(6)°, and Z = 2; the structure was refined to R = 0.064. 2 is a trinuclear complex with two (Me2NCH2CH2CH2)Cr-(?-Cl) 2 fragments attached either side of a central Mg atom through four Cr-Cl-Mg bridges. (literal)

Prodotto di

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• FRANCO OSSOLA (Unità di personale interno)
• UMBERTO CASELLATO (Persona)

Insieme di parole chiave

• Keywords of "Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR di

• UMBERTO CASELLATO (Persona)
• FRANCO OSSOLA (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)

Insieme di parole chiave di

• Keywords of "Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2" (Insieme di parole chiave)