http://www.cnr.it/ontology/cnr/individuo/prodotto/ID216408
MOCVD route to chromium carbonitride thin films using Cr(NEt2)(4) as single-source precursor: Growth and mechanism (Articolo in rivista)
- Type
- Label
- MOCVD route to chromium carbonitride thin films using Cr(NEt2)(4) as single-source precursor: Growth and mechanism (Articolo in rivista) (literal)
- Anno
- 1997-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/cvde.19970030305 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Ossola F.; Maury F. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://onlinelibrary.wiley.com/doi/10.1002/cvde.19970030305/abstract;jsessionid=C6BE385971442967FE83D317A96CB5BF.d02t03 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Scopu (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1 Ist. Chim. Tecnologie Inorganiche M., Area della Ricerca del CNR, Corso Stati Uniti 4, I-35127 Padova, Italy /
2 Lab. Reactiv. et Protect. des Mat., CNRS-INPT, Ecl. Natl. Sup. de Chimie, 118 Route de Narbonne, F-31077 Toulouse Cedex 4, France (literal)
- Titolo
- MOCVD route to chromium carbonitride thin films using Cr(NEt2)(4) as single-source precursor: Growth and mechanism (literal)
- Abstract
- Chromium carbonitride coatings with a low nitrogen content were deposited by low pressure MOCVD in the temperature range 573-793 K using Cr(NEt2)(4) as single-source precursor. As-deposited films are amorphous and crystallize upon annealing at 873 K to form an orthorhombic ternary phase. They exhibit a high hardness and their resistivity decreases by increasing the growth temperature. This dependence has been correlated to their microstructure. Quantitative H-1 NMR analysis of the by-products of the MOCVD reaction has been performed. The quasi-equimolecular ratio of the by-products EtN=CHMe and HNEt2 suggests that most of the NEt2 ligands are removed by a stepwise mechanism, which is discussed. (literal)
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