First heterodifunctional ligand derived from a tetradentate phosphine: synthesis and characterization of cis,trans,cis-1,3-bis?diphenylphosphino/ 2,4-bis?diphenylphosphinothioyl/ cyclobutane and its complex with PdCl2 (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• First heterodifunctional ligand derived from a tetradentate phosphine: synthesis and characterization of cis,trans,cis-1,3-bis?diphenylphosphino/ 2,4-bis?diphenylphosphinothioyl/ cyclobutane and its complex with PdCl2 (Articolo in rivista) (literal)

Anno

• 2000-01-01T00:00:00+01:00 (literal)

Alternative label

• Stampfl, Thomas; Haid, Rainer; Langes, Christoph; Oberhauser, Werner; Bachmann, Christian; Kopacka, Holger; Ongania, Karl-Hans; Brueggeller, Peter (2000)
  First heterodifunctional ligand derived from a tetradentate phosphine: synthesis and characterization of cis,trans,cis-1,3-bis?diphenylphosphino/ 2,4-bis?diphenylphosphinothioyl/ cyclobutane and its complex with PdCl2
  in Inorganic chemistry communications
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Stampfl, Thomas; Haid, Rainer; Langes, Christoph; Oberhauser, Werner; Bachmann, Christian; Kopacka, Holger; Ongania, Karl-Hans; Brueggeller, Peter (literal)

Pagina inizio

• 387 (literal)

Pagina fine

• 392 (literal)

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• 3 (literal)

Rivista

• Inorganic chemistry communications (Rivista)

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• 6 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR Institut f uer Allgemeine, Anorganische und Theoretische Chemie, Universitaet Innsbruck, Innrain 52a, 6020 Innsbruck, Austria Institut f uer Organische Chemie, Universitaett Innsbruck, Innrain 52a, 6020 Innsbruck, Austria (literal)

Titolo

• First heterodifunctional ligand derived from a tetradentate phosphine: synthesis and characterization of cis,trans,cis-1,3-bis?diphenylphosphino/ 2,4-bis?diphenylphosphinothioyl/ cyclobutane and its complex with PdCl2 (literal)

Abstract

• Cis,trans,cis-1,2,3,4-tetrakisdiphenylphosphino.cyclobutane dppcb. can be selectively oxidized by S in toluene to the disulfide cis,trans,cis-1,3-bisdiphenylphosphino.-2,4-bisdiphenylphosphinothioyl.cyclobutane dppcbS2.. DppcbS2 is the first heterodifunctional ligand derived from a tetradentate phosphine obtained with good yield and high purity. It reacts with two equivalents of PdCl2 producing wPd2Cl4dppcbS2.x 1.. Both dppcbS2 and 1 have been fully characterized by X-ray structure analyses, NMR spectroscopy 31P?1H4, 13C?1H4, 1H., FAB mass spectrometry, elemental analyses and melting points. The possible catalytic applications of the versatile heterodifunctional ligand dppcbS2 are discussed in view of the two X-ray structures of dppcbS2 and 1. (literal)

Prodotto di

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR

• WERNER OBERHAUSER (Unità di personale interno)

Insieme di parole chiave

• Keywords of "First heterodifunctional ligand derived from a tetradentate phosphine: synthesis and characterization of cis,trans,cis-1,3-bis?diphenylphosphino/ 2,4-bis?diphenylphosphinothioyl/ cyclobutane and its complex with PdCl2" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR di

• WERNER OBERHAUSER (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry communications (Rivista)

Insieme di parole chiave di

• Keywords of "First heterodifunctional ligand derived from a tetradentate phosphine: synthesis and characterization of cis,trans,cis-1,3-bis?diphenylphosphino/ 2,4-bis?diphenylphosphinothioyl/ cyclobutane and its complex with PdCl2" (Insieme di parole chiave)