Ion beam induced reduction of metallic cations in yttria-zirconia (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Ion beam induced reduction of metallic cations in yttria-zirconia (Articolo in rivista) (literal)

Anno

• 1996-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/0168-583X(96)00085-7 (literal)

Alternative label

• G.M. Ingo, G. Marletta (1996)
  Ion beam induced reduction of metallic cations in yttria-zirconia
  in Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms (Print); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• G.M. Ingo, G. Marletta (literal)

Pagina inizio

• 440 (literal)

Pagina fine

• 446 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 116 (literal)

Rivista

• Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1-4 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• G.M. Ingo [1], G. Marletta [2] [1] Istituto di Chimica dei Materiali-CNR, Area della Ricerca di Roma 1, via Salaria Km 29.3, 00015 Monterotondo, Rome, Italy. [2] Università della Basilicata,DIPARTIMENTO CHIMICA, I-85100 POTENZA, ITALY (literal)

Titolo

• Ion beam induced reduction of metallic cations in yttria-zirconia (literal)

Abstract

• Samples consisting in polycrystalline films of 8 wt.% Y2O3-ZrO2, 0.8 mm thick, deposited by plasma spray technique, were irradiated with 1-4 keV Ar ions in the fluence range between 1 x 10(16) and 7 x 10(17) ions/cm(2). The formation of radiation-induced Zr(III) and Zr(II) as well as Y(II) suboxides is demonstrated by using X-ray photoelectron spectroscopy (XPS). In particular, reduced species start to be observed when the energy of the irradiating ions is higher than 1 keV, while the relative amount of the low valence cations produced for a given fluence in the altered layer has been found to depend on the primary ion energy. The results obtained by angular dependent XPS (ADXPS) analysis suggest that the in-depth distribution of the Zr and Y reduced species also depends on the primary ion energy, In particular, for samples irradiated with 2 keV Ar ions the Zr (and Y) reduced species are detected at the surface, while for samples irradiated with 4 keV ions the reduced species are found to be mostly localized in depth. The observed irradiation effects are explained in terms of bombardment-induced Gibbsian segregation (BIS) mechanism. (literal)

Editore

• ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS (Editore)

Prodotto di

• Sintesi e crescita di film e superfici nanostrutturate (PM.P05.004.002) (Modulo)
• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)

Autore CNR

• GABRIEL MARIA INGO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Ion beam induced reduction of metallic cations in yttria-zirconia" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)
• Sintesi e crescita di film e superfici nanostrutturate (PM.P05.004.002) (Modulo)

Autore CNR di

• GABRIEL MARIA INGO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms (Rivista)

Editore di

• ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS (Editore)

Insieme di parole chiave di

• Keywords of "Ion beam induced reduction of metallic cations in yttria-zirconia" (Insieme di parole chiave)