A comb-like alternating copolymer of thiophene and hydroxyalkylthiophene: synthesis and characterization (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• A comb-like alternating copolymer of thiophene and hydroxyalkylthiophene: synthesis and characterization (Articolo in rivista) (literal)

Anno

• 2001-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/1521-3935(20011201)202:18<3477::AID-MACP3477>3.0.CO;2-5 (literal)

Alternative label

• A. Bolognesi, F. Bertini, M. Marinelli, W. Porzio (2001)
  A comb-like alternating copolymer of thiophene and hydroxyalkylthiophene: synthesis and characterization
  in Macromolecular chemistry and physics (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• A. Bolognesi, F. Bertini, M. Marinelli, W. Porzio (literal)

Pagina inizio

• 3477 (literal)

Pagina fine

• 3483 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/doi/10.1002/1521-3935(20011201)202:18%3C3477::AID-MACP3477%3E3.0.CO;2-5/pdf (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 202 (literal)

Rivista

• Macromolecular chemistry and physics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica delle Macromolecole CNR (literal)

Titolo

• A comb-like alternating copolymer of thiophene and hydroxyalkylthiophene: synthesis and characterization (literal)

Abstract

• The synthesis and characterization of an alternating copolymer formed by thiophene and alkylated thiophene obtained by means of Ni (Yamamoto method) and Pd (Suzuki coupling) is reported here. The side chain of the alkylated monomer contains a tetrahydropyranyl group which can be removed leaving the --OH function free. The copolymers obtained with the two different synthetic procedures are almost equivalent, with the exceptions that the one prepared using Pd has a strictly alternating structure, while the copolymer from Ni contains some enchainment irregularities, hence a rigorously alternating structure is not reached. The copolymer from Pd has been characterized in its deprotected form by XRD analysis and DSC. When the protective groups are removed, interchain hydrogen bond formation occurs, leading to a structure exhibiting a certain degree of order (at least bidimensional) with a high melting point. Graphite-like interchain spacing (3.5 Å) observed after annealing is indicative of a very planar backbone. (literal)

Prodotto di

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)

Autore CNR

• FABIO BERTINI (Unità di personale interno)
• WILLIAM UMBERTO PORZIO (Unità di personale interno)
• ALBERTO BOLOGNESI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "A comb-like alternating copolymer of thiophene and hydroxyalkylthiophene: synthesis and characterization" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)

Autore CNR di

• FABIO BERTINI (Unità di personale interno)
• WILLIAM UMBERTO PORZIO (Unità di personale interno)
• ALBERTO BOLOGNESI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecular chemistry and physics (Rivista)

Insieme di parole chiave di

• Parole chiave di "A comb-like alternating copolymer of thiophene and hydroxyalkylthiophene: synthesis and characterization" (Insieme di parole chiave)