Key ingredients of the alkali atom - metal surface interaction: Chemical bonding versus spectral properties (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Key ingredients of the alkali atom - metal surface interaction: Chemical bonding versus spectral properties (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.progsurf.2013.03.002 (literal)

Alternative label

• Trioni, M.I.; Achilli, S.; Chulkov, E.V. (2013)
  Key ingredients of the alkali atom - metal surface interaction: Chemical bonding versus spectral properties
  in Progress in surface sScience (Print); Academic Press Elsevier, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Trioni, M.I.; Achilli, S.; Chulkov, E.V. (literal)

Pagina inizio

• 160 (literal)

Pagina fine

• 170 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S007968161300018X (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 88 (literal)

Rivista

• Progress in surface sScience (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 11 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR National Research Council of Italy, ISTM, via Golgi 19, I-20133 Milan, Italy [Trioni] Dipartimento di Scienza dei Materiali, Università di Milano-Bicocca, via Cozzi 53, I-20125 Milano, Italy [Achilli] Donostia International Physics Center (DIPC), Paseo Manuel de Lardizabal 4, San Sebastian E-20018, Spain [Trioni, Achilli, Chulkov] (literal)

Titolo

• Key ingredients of the alkali atom - metal surface interaction: Chemical bonding versus spectral properties (literal)

Abstract

• The interaction of alkali atoms with metal surfaces is reviewed. The peculiar electronic configuration of such atoms, with only one valence electron participating in the bond formation, suggested simple pictures to describe their interaction with a metal surface. But it was early evident that the adsorption properties depend on many aspects, related to the electronic structure of constituents, leading, for example, to different degrees of ionicity/covalency of the alkali atom-metal bond. Sophisticated theoretical modeling tried to shed light on this aspect. The spectral properties are the ultimate features in determining how the systems interact with each other. In this review the electronic and spectral properties are discussed focusing on different theoretical representations of the physical system and on their consequences. Surface projected energy gaps of the substrate as well as the substrate continuous spectrum are key aspects in determining the nature of the interac- tion and bonding with alkali adsorbates. (literal)

Editore

• Academic Press Elsevier (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Nanoingegneria chimica ab-initio: struttura, legame e proprieta' di materiali di interesse tecnologico e dinamica di nanosistemi per il controllo della loro reattivita' chimica (PM.P07.002.003) (Modulo)

Autore CNR

• MARIO ITALO TRIONI (Persona)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Nanoingegneria chimica ab-initio: struttura, legame e proprieta' di materiali di interesse tecnologico e dinamica di nanosistemi per il controllo della loro reattivita' chimica (PM.P07.002.003) (Modulo)

Autore CNR di

• MARIO ITALO TRIONI (Persona)

Editore di

• Academic Press Elsevier (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Progress in surface sScience (Rivista)