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Structure alterations in microporous (Mg,Fe)2Al4Si5O18 crystals induced by energetic heavy-ion irradiation (Articolo in rivista)
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- Label
- Structure alterations in microporous (Mg,Fe)2Al4Si5O18 crystals induced by energetic heavy-ion irradiation (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.jssc.2010.07.038 (literal)
- Alternative label
Miletich R., Gatta G.D., Redhammer G.J., Burchard M., Meyer H.P., Weikusat C., Rotiroti N. Glasmacher U.A., Trautmann C., Neumann R. (2010)
Structure alterations in microporous (Mg,Fe)2Al4Si5O18 crystals induced by energetic heavy-ion irradiation
in Journal of solid state chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Miletich R., Gatta G.D., Redhammer G.J., Burchard M., Meyer H.P., Weikusat C., Rotiroti N. Glasmacher U.A., Trautmann C., Neumann R. (literal)
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- Mineral physics (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Institut fuer Geowissenschaften, Universitaet Heidelberg, Im Neuenheimer Feld 234-236, D-69120 Heidelberg, Germany;
Dipartimento di Scienze della Terra, Universita' degli Studi di Milano, Via Botticelli 23, I-20133 Milano, Italy;
Fachbereich Materialforschung und Physik, Abteilung Mineralogie, Universitaet Salzburg, Hellbrunnerstrasse 34, A-5020 Salzburg, Austria;
GSI Helmholtzzentrum fuer Schwerionenforschung, Materials Research, Planckstrasse 1, D-64291 Darmstadt, Germany (literal)
- Titolo
- Structure alterations in microporous (Mg,Fe)2Al4Si5O18 crystals induced by energetic heavy-ion irradiation (literal)
- Abstract
- The microporous framework structure of (Mg1-xFex)2Al4Si5O18 (cordierite) has been subject to a
comparative study on the effect of structural alterations originating from exposure to high-energy
heavy ions. Oriented samples (with x . 0.061, 0.122, and 0.170) were irradiated with swift 124Xe, 197Au
and 96Ru ions with 11.1 MeV per nucleon energy and fluences of 1 x 10^12 and 1 x 10^13 ions/cm2.
Irradiated and non-irradiated samples were investigated by means of X-ray diffraction, Mossbauer
spectroscopy and optical absorption spectroscopy. Structural investigations reveal an essentially
unchanged Al,Si ordering, which appears to be unaffected by irradiation. The most remarkable
macroscopic change is the ion-beam induced colouration, which could be assigned to electronic charge
transfer transitions involving the Fe cations. Mossbauer spectra indicate an increased amount of [4]Fe3+
for the irradiated sample. The most noticeable structural alteration concerns irradiation-induced
dehydration of extra-framework H2O, which is accompanied by a reduction in the molar volume by
0.2 vol%. (literal)
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