Efficient Anodically Grown WO3 for Photoelectrochemical Water Splitting (Articolo in rivista)

Type
Label
  • Efficient Anodically Grown WO3 for Photoelectrochemical Water Splitting (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.egypro.2012.05.214 (literal)
Alternative label
  • S. Caramori [ 1 ], V. Cristino [ 1 ], L. Meda [ 2 ], A. Tacca [ 2 ], R. Argazzi [ 3 ], C. A. Bignozzi [ 1 ] (2012)
    Efficient Anodically Grown WO3 for Photoelectrochemical Water Splitting
    in Energy procedia (Online); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • S. Caramori [ 1 ], V. Cristino [ 1 ], L. Meda [ 2 ], A. Tacca [ 2 ], R. Argazzi [ 3 ], C. A. Bignozzi [ 1 ] (literal)
Pagina inizio
  • 127 (literal)
Pagina fine
  • 136 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 22 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • [ 1 ] Univ Ferrara, Dipartimento Chim, I-44121 Ferrara, Italy [ 2 ] Ist Guido Donegani SpA, ENI, I-28100 Novara, Italy [ 3 ] ISOF-CNR c/o Univ Ferrara, Dipartimento Chim, I-44121 Ferrara, Italy (literal)
Titolo
  • Efficient Anodically Grown WO3 for Photoelectrochemical Water Splitting (literal)
Abstract
  • The potentiostatic anodization of metallic tungsten has been investigated in different solvent/electrolyte compositions with the aim of improving the photoelectrochemical performances of the tungsten oxide layer. Among the explored electrolytes, the anodization in the NMF/H2O/NH4F solvent mixture was found to produce the most efficient WO3 photoanodes, which, combining spectral sensitivity, high electrochemically active surface and improved charge transfer kinetics, outperform, under simulated solar illumination, most of the reported nanocrystalline substrates produced by anodization in aqueous electrolytes and by sol gel methods. While the preparation of the photoelectrodes is a slow process at room temperature (20 degrees C), it could be greatly accelerated (x 10) by carrying out the anodization at 40-50 degrees C, thus proving to be a fast and convenient approach to the production of high performing WO3 photoactive substrates directly connected to a metal electron collector. (literal)
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