One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/c2gc16524d (literal)

Alternative label

• Coccia F, Tonucci L, Bosco D, Bressan M, d'Alessandro N. (2012)
  One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in
  in Green chemistry (Print); ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE,, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Coccia F, Tonucci L, Bosco D, Bressan M, d'Alessandro N. (literal)

Pagina inizio

• 1073 (literal)

Pagina fine

• 1078 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/Content/ArticleLanding/2012/GC/c2gc16524d (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 14 (literal)

Rivista

• Green chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 6 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 4 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• GD Annunzio Univ Chieti & Pescara, Dept Sci, I-65127 Pescara, Italy GD Annunzio Univ Chieti & Pescara, Dept Philosophy Human & Educ Sci, I-66013 Chieti, Italy CNR, Inst Mol Genet, Dept Biomorphol Sci, I-66013 Chieti, Italy GD Annunzio Univ Chieti & Pescara, Dept Engn & Geotechnol, I-65127 Pescara, Italy (literal)

Titolo

• One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in (literal)

Abstract

• A one-pot green method to synthesise Pt and Pd nanoparticles is reported. Two natural aromatic polymers, lignin and fulvic acid, were used as both reducing and stabilising agents at moderate temperature (80 degrees C) in water and under aerobic conditions. Full characterisation was performed using TEM, UV-vis, XRD, Pt-195 and H-1 NMR, FT-IR and GC-MS techniques. In the TEM images, we observed spherical nanoparticles of diameters in the range of 16 nm to 20 nm, in the case of Pd, and smaller ones of not so well defined shapes for Pt. GC-MS of the organic fractions formed during the preparation of the nanoparticles showed defined amounts of vanillin, a well known degradation product of these polymers. This finding indicates that the active participation of lignins and fulvic acids in the metal reduction step. The catalytic activity of the nanoparticles was tested for the NaBH4 reduction of 4-nitrophenol and for the aerobic oxidation of alcohols, reactions that are always conducted under green conditions. Both Pt and Pd nanoparticles show good catalytic activity in the reduction reaction, while in the aerobic oxidation reaction only the Pt nanoparticles were effective (literal)

Editore

• ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, (Editore)

Prodotto di

• Institute of molecular genetics (IGM) (Istituto)
• Bersagli molecolari per il controllo della progressione tumorale (ME.P03.012.001) (Modulo)

Autore CNR

• DOMENICO BOSCO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of molecular genetics (IGM) (Istituto)
• Bersagli molecolari per il controllo della progressione tumorale (ME.P03.012.001) (Modulo)

Autore CNR di

• DOMENICO BOSCO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Green chemistry (Rivista)

Editore di

• ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, (Editore)

Insieme di parole chiave di

• Keywords of "One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in" (Insieme di parole chiave)