http://www.cnr.it/ontology/cnr/individuo/prodotto/ID199172
Bi-axially aligned crystallites of a fluorene-bithiophene co-polymer (Articolo in rivista)
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- Label
- Bi-axially aligned crystallites of a fluorene-bithiophene co-polymer (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.eurpolymj.2012.10.014 (literal)
- Alternative label
O. Werzer , W. Porzio , G. Trimmel , H. Plank , R. Resel (2013)
Bi-axially aligned crystallites of a fluorene-bithiophene co-polymer
in European Polymer Journal; Elsevier, Oxford (Regno Unito)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- O. Werzer , W. Porzio , G. Trimmel , H. Plank , R. Resel (literal)
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- http://dx.doi.org/10.1016/j.eurpolymj.2012.10.014 (literal)
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- ISI Web of Science (WOS) (literal)
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- Institute of Pharmaceutical Sciences, Department of Pharmaceutical Technology, Karl-Franzens University, Graz, Austria
b Institute of Solid State Physics, Graz University of Technology, Austria
c Instituto per lo Studio delle Macromolecole, Consiglio Nazionale delle Ricerche, Milano, Italy
d Institute for Chemistry and Technology of Materials, Graz University of Technology, Austria
e Christian Doppler Laboratory for Nanocomposite Solar Cells, Graz University of Technology, Austria
f Institute for Electron Microscopy, Graz University of Technology, Austria (literal)
- Titolo
- Bi-axially aligned crystallites of a fluorene-bithiophene co-polymer (literal)
- Abstract
- Thin films of the soluble conjugated poly(9,9-dioctylfluorenyl-co-bithiophene) (F8T2) on
top of polyimide surfaces were investigated by X-ray diffraction measurements, atomic
force and optical microscopy. In-situ temperature dependent specular X-ray diffraction
experiments reveal the formation crystallites on heating. An orthorhombic unit cell of
a = 1.61 nm, b = 1.28 nm and c = 6.2 nm was found which results in 16 monomer units
being hosted in the unit cell at a density of 1.15 g cm?3. Morphology investigations reveal
random azimutal orientations of spherulite like structures are present for samples prepared
on the isotropic surface. Using a defined preparation route allowed for the alignment
of the crystallites with respect of a rubbed polyimide surface resulting in bi-axially aligned
F8T2 crystals as determined by X-ray diffraction polefigure measurements and optical
microscopy. (literal)
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