http://www.cnr.it/ontology/cnr/individuo/prodotto/ID199067
Ferroelectric switching in Bi4Ti3O12 nanorods (Articolo in rivista)
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- Ferroelectric switching in Bi4Ti3O12 nanorods (Articolo in rivista) (literal)
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- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1109/TUFFC.2012.2405 (literal)
- Alternative label
Azodi M.; Harnagea C.; Buscaglia V.; Buscaglia M.; Nanni P.; Rosei F.; Pignolet A. (2012)
Ferroelectric switching in Bi4Ti3O12 nanorods
in IEEE transactions on ultrasonics, ferroelectrics, and frequency control (Online); Institute of Electrical and Electronics Engineers, NEW York (Stati Uniti d'America)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Azodi M.; Harnagea C.; Buscaglia V.; Buscaglia M.; Nanni P.; Rosei F.; Pignolet A. (literal)
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- 1,2,6,7 : Centre Energie, Materiaux et Telecommunications, Institut National de la Recherche Scientifique, Varennes, QC, Canada /
3,4,5 : Electroceramics Department, Institute of Energetics and Interphases, Genoa, Italy (literal)
- Titolo
- Ferroelectric switching in Bi4Ti3O12 nanorods (literal)
- Abstract
- We report the piezoelectric and ferroelectric properties of individual one-dimensional objects made of Bi 4Ti 3O 12 (BiT). The nanorods and nanowires investigated in this study were fabricated by a two-step process: 1) preparation of reactive templates using hydrothermal-like synthesis and colloidal chemistry and 2) transformation of the reactive templates in Bi 4Ti 3O 12 by solid-state reaction, overcoming the morphological instability problem of 1-D templates. Using piezoresponse force microscopy (PFM) with both out-of-plane and in-plane detection capability, we show that both types of objects exhibit strong piezoelectric activity and good switching ferroelectric behavior. Analysis of the PFM hysteresis loops obtained revealed that the coercive voltage of the in-plane PFM signal can be either equal to or different from that of the out-of-plane response. We associate these situations with two types of polarization switching mechanisms: direct 180°switching, and via rotation of polarization, resulting from the independent switching of the components along the a- and ccrystallographic axes. In a few instances, we observe a negative piezoelectric coefficient, which we explain by the specific shape of the piezoelectric surface of Bi 4Ti 3O 12. (literal)
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