Enhanced performance of the catalytic conversion of allyl alcohol to 3- hydroxypropionic acid using bimetallic gold catalysts (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Enhanced performance of the catalytic conversion of allyl alcohol to 3- hydroxypropionic acid using bimetallic gold catalysts (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Alternative label

• E. Falletta, C. Della Pina, M. Rossi, Q. He, C.J. Kiely, G. J. Hutchings (2011)
  Enhanced performance of the catalytic conversion of allyl alcohol to 3- hydroxypropionic acid using bimetallic gold catalysts
  in Faraday discussions (Print); Royal Society of Chemistry, Cambridge (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• E. Falletta, C. Della Pina, M. Rossi, Q. He, C.J. Kiely, G. J. Hutchings (literal)

Pagina inizio

• 367 (literal)

Pagina fine

• 379 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 152 (literal)

Rivista

• Faraday discussions (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università degli Studi di Milano, Dip. Chimica, ISTM-CNR (E. Falletta, C. Della Pina, M. Rossi); Lehigh University - Department of Material Science and Engineering - USA (Q. He, C.J. Kiely); Cardiff University - Cardiff Catalysis Institute, School of Chemistry - UK (G. J. Hutchings) (literal)

Titolo

• Enhanced performance of the catalytic conversion of allyl alcohol to 3- hydroxypropionic acid using bimetallic gold catalysts (literal)

Abstract

• One of the strategic building blocks in organic synthesis is 3-hydroxypropionic acid, which is particularly important for the manufacture of high performance polymers. However, to date, despite many attempts using both biological and chemical routes, no large scale effective process for manufacturing 3-hydroxypropionic acid has been developed. One potentially useful starting point is from allyl alcohol, as this can be obtained in principle from the dehydration of glycerol, thereby presenting a bio-renewable green pathway to this important building block. The catalytic transformation of allyl alcohol to 3-hydroxypropionic acid presents interesting challenges in catalyst design, particularly with respect to the control of selectivity among the products that can be expected, as acrylic acid, acrolein and glyceric acid can also be formed. In this paper, we present a novel eco-sustainable catalytic pathway leading to 3-hydroxypropionic acid, which highlights the outstanding potential of gold based and bimetallic catalysts in the aerobic oxidation of allyl alcohol. (literal)

Editore

• Royal Society of Chemistry (Editore)

Prodotto di

• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• cristina della pina (Unità di personale esterno)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR di

• cristina della pina (Unità di personale esterno)

Editore di

• Royal Society of Chemistry (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Faraday discussions (Rivista)