EPR analysis of La1-xMxMnO3+y (M=Ce, Sr) perovskite-like structured catalysts for the methane flameless combustion (Articolo in rivista)

Type
Label
  • EPR analysis of La1-xMxMnO3+y (M=Ce, Sr) perovskite-like structured catalysts for the methane flameless combustion (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/ic300977e (literal)
Alternative label
  • C. Oliva*, M. Allieta, M. Scavini, C. Biffi, I. Rossetti, L. Forni (2012)
    EPR analysis of La1-xMxMnO3+y (M=Ce, Sr) perovskite-like structured catalysts for the methane flameless combustion
    in Inorganic chemistry
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • C. Oliva*, M. Allieta, M. Scavini, C. Biffi, I. Rossetti, L. Forni (literal)
Pagina inizio
  • 8433 (literal)
Pagina fine
  • 8440 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 51 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 8 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1) Dipartimento di Chimica, Universita? degli Studi di Milano 2) CNR-ISTM, Via C. Golgi 19, 20133 Milano, Italy (literal)
Titolo
  • EPR analysis of La1-xMxMnO3+y (M=Ce, Sr) perovskite-like structured catalysts for the methane flameless combustion (literal)
Abstract
  • The physical-chemical properties of some nanostructured perovskitelike catalysts of general formula La1-xMxMnO3+? (M = Ce, Sr) have been investigated, in particular by using the electron paramagnetic resonance (EPR) technique. We show that the interplay between the -O-Mn3+-O-Mn4+-O- electron double-exchange and the electron mobility is strictly dependent on the dopant nature and the annealing conditions in air. A relationship between the observed properties of these samples and their activity in the methane flameless catalytic combustion is proposed (literal)
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