Molecular description of the propagation of chirality from molecules to complex systems: different mechanisms controlled by hydrophobic interactions (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Molecular description of the propagation of chirality from molecules to complex systems: different mechanisms controlled by hydrophobic interactions (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/chem.201202342 (literal)

Alternative label

• F. Marinelli, A. Sorrenti, V. Corvaglia, V. Leone, G. Mancini (2012)
  Molecular description of the propagation of chirality from molecules to complex systems: different mechanisms controlled by hydrophobic interactions
  in Chemistry - A European Journal; WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (Germania)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• F. Marinelli, A. Sorrenti, V. Corvaglia, V. Leone, G. Mancini (literal)

Pagina inizio

• 14680 (literal)

Pagina fine

• 14688 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 18 (literal)

Rivista

• Chemistry - A European Journal (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Note

• Scopus (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Theoretical Molecular Biophysics Group, Max Planck Institute of Biophysics Max-von-Laue Strasse 3, 60438 Frankfurt am Main (Germany) CNR, Istituto di Metodologie Chimiche (IMC) and Dipartimento di Chimica Università degli Studi di Roma \"La Sapienza\" P.le A. Moro 5, 00185 Roma (Italy) Centro di Eccellenza Materiali Innovativi Nanostrutturati per Applicazioni Chimiche Fisiche e Biomediche (CEMIN)Via Elce di Sotto 8, 06123 Perugia (Italy) (literal)

Titolo

• Molecular description of the propagation of chirality from molecules to complex systems: different mechanisms controlled by hydrophobic interactions (literal)

Abstract

• In this work a combined theoretical and experimental approach was used to elucidate and describe at the molecular level the basic interactions that drive the transfer of the chiral information from chiral surfactant molecules to dye/surfactant assemblies. It was found that both hydrophobic interactions and relative concentrations strongly influence the chiropticalfeatures of the heteroaggregates. In particular it was observed that, depending on the length of the surfactant hydrophobic chain, the chiral information is transferred to the dye by stabilizing an enantiomer either of a chiral conformer or of a chiral topological arrangement. These findings underline the role of hydrophobic interactions in the transfer of chirality and provide an example of the potential of in silico simulations for providing an accurate description of the process of chirality propagation. (literal)

Editore

• WILEY-VCH Verlag GmbH & Co. KGaA (Editore)

Prodotto di

• Istituto di metodologie chimiche (IMC) (Istituto)
• Metodologie, nanoparticelle e nutraceutici in nanomedicina (PM.P05.002.001) (Modulo)

Autore CNR

• GIOVANNA MANCINI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Molecular description of the propagation of chirality from molecules to complex systems: different mechanisms controlled by hydrophobic interactions" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di metodologie chimiche (IMC) (Istituto)
• Metodologie, nanoparticelle e nutraceutici in nanomedicina (PM.P05.002.001) (Modulo)

Autore CNR di

• GIOVANNA MANCINI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry - A European Journal (Rivista)

Editore di

• WILEY-VCH Verlag GmbH & Co. KGaA (Editore)

Insieme di parole chiave di

• Keywords of "Molecular description of the propagation of chirality from molecules to complex systems: different mechanisms controlled by hydrophobic interactions" (Insieme di parole chiave)