Enantiomeric separation by capillary electrophoresis using a soluble neutral ?-cyclodextrin polymer (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Enantiomeric separation by capillary electrophoresis using a soluble neutral ?-cyclodextrin polymer (Articolo in rivista) (literal)

Anno

• 1995-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/0021-9673(95)00107-X (literal)

Alternative label

• INGELSE B, EVERAERTS FM, DESIDERIO C, FANALI S (1995)
  Enantiomeric separation by capillary electrophoresis using a soluble neutral ?-cyclodextrin polymer
  in Journal of chromatography (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• INGELSE B, EVERAERTS FM, DESIDERIO C, FANALI S (literal)

Pagina inizio

• 89 (literal)

Pagina fine

• 98 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 709 (literal)

Rivista

• Journal of chromatography (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• University of Eindhoven; University of Eindhoven; IMC-CNR; IMC-CNR (literal)

Titolo

• Enantiomeric separation by capillary electrophoresis using a soluble neutral ?-cyclodextrin polymer (literal)

Abstract

• Enantiomers of several racemic basic compounds of pharmaceutical interest and three tryptophan derivatives were investigated by capillary electrophoresis employing a soluble ?-cyclodextrin polymer and native ?-cyclodextrin. The effects of the concentration of the polymer added to the background electrolyte and of the pH of the buffer on the effective mobility and resolution of the studied compounds were examined. The p-cyclodextrin polymer showed a higher stereoselectivity than the parent ?-cyclodextrin. Enantioselectivity and resolution were influenced by the concentration of the ?-cyclodextrin polymer and the background electrolyte. A pH study, carried out in the pH range 2.7-6, showed that an increase in pH caused a general decrease in both resolution and selectivity. The best results for the enantiomeric separation of the basic compounds studied were obtained at pH 2.7. (literal)

Prodotto di

• Sviluppo di metodologie chimiche avanzate per lo studio di fenomeni delle scienze omiche (PM.P06.019.001) (Modulo)
• Istituto di metodologie chimiche (IMC) (Istituto)

Autore CNR

• SALVATORE FANALI (Unità di personale interno)
• CLAUDIA DESIDERIO (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di metodologie chimiche (IMC) (Istituto)
• Sviluppo di metodologie chimiche avanzate per lo studio di fenomeni delle scienze omiche (PM.P06.019.001) (Modulo)

Autore CNR di

• SALVATORE FANALI (Unità di personale interno)
• CLAUDIA DESIDERIO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of chromatography (Rivista)