Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone (Articolo in rivista) (literal)

Anno

• 2001-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/om0010868 (literal)

Alternative label

• Bianchini C., Frediani M., Mantovani G., Vizza F. (2001)
  Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bianchini C., Frediani M., Mantovani G., Vizza F. (literal)

Pagina inizio

• 2660 (literal)

Pagina fine

• 2662 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 20 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR; Università di Firenze (literal)

Titolo

• Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone (literal)

Abstract

• A p-styrenyl substituent attached to the ligand framework allows the diphosphine moiety -(C6H4)CH2-OCH2C(CH3)(CH2PPh2)2 to be introduced as a pendant group in cross-linked styrene/divinylbenzene matrixes via free-radical copolymerization. In conjunction with rhodium(I), the POLYDIPHOS material forms an effective heterogeneous catalyst for the hydrogenation of benzylideneacetone to benzylacetone and of quinoline to a mixture of 1,2,3,4-tetrahydroquinoline, 5,6,7,8-tetrahydroquinoline, and decahydroquinoline. The homogeneous behavior of related 1,3-bis(diphenylphosphino)- propane rhodium complexes is different in both activity and selectivity. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• CLAUDIO BIANCHINI (Persona)
• FRANCESCO VIZZA (Unità di personale interno)
• ANDREA MELI (Persona)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR di

• FRANCESCO VIZZA (Unità di personale interno)
• CLAUDIO BIANCHINI (Persona)
• ANDREA MELI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)