Synthesis of cis- and trans-polyisoprene adduct with nitrogen dioxide (NO2/N2O4 mixture) and a study of the thermal stability of the adduct (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Synthesis of cis- and trans-polyisoprene adduct with nitrogen dioxide (NO2/N2O4 mixture) and a study of the thermal stability of the adduct (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.polymdegradstab.2012.04.009 (literal)

Alternative label

• F. Cataldo, O. Ursini , C. Cherubini, S. Rocchi (2012)
  Synthesis of cis- and trans-polyisoprene adduct with nitrogen dioxide (NO2/N2O4 mixture) and a study of the thermal stability of the adduct
  in Polymer degradation and stability
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• F. Cataldo, O. Ursini , C. Cherubini, S. Rocchi (literal)

Pagina inizio

• 1090 (literal)

Pagina fine

• 1100 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 97 (literal)

Rivista

• Polymer degradation and stability (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università Tor Vergata, Department of Chemistry, Via della Ricerca Scientifica, Rome, Italy Lupi Chemical Research Institute, Via Casilina 1626/A, 00133 Rome, Italy Institute of Chemical Methodologies, CNR, Via Salaria Km. 29,300, 00016 Monterotondo, Stazione, Rome, Italy. (literal)

Titolo

• Synthesis of cis- and trans-polyisoprene adduct with nitrogen dioxide (NO2/N2O4 mixture) and a study of the thermal stability of the adduct (literal)

Abstract

• Tetrahydrofuran solutions of cis- or trans-polyisoprene react rapidly with a NO2/N2O4 mixture without crosslinking and gelation of the solution (as happens in other solvents) and with formation of a dinitro adduct (nitro-cis-PIP and nitro-trans-PIP) as the main product. The chemical structure of the adduct was analyzed by FT-IR and UV spectroscopy revealing that species other than the nitro (-NO2) groups are also present in the adduct, like for instance the nitrate group (eONO2). The thermal stability of the adduct was studied by the thermogravimetric analysis (TGA-DTG) combined with differential thermal analysis (DTA). The initial decomposition of the adduct is exothermic and the release of heat reaches its maximum at about 200 °C and the completion of the exothermic decomposition occurs at about 325 °C. The amount of nitro groups present in the adduct was determined by the TGA-DTG. The decomposition of the adduct was also followed by the TGA-FTIR analytical technique and a certain number of volatile and gaseous species were detected ranging from mixtures of nitrogen oxides and nitroalkanes to NH3, HCN and CH4. The adduct nitro-cis-PIP and nitro-trans-PIP yield a carbon foam even at 400 °C which can be defined as a crosslinked vitreous carbon foam which was studied by FT-IR spectroscopy (literal)

Prodotto di

• Metodologie chimiche e radiochimiche per lo sviluppo di materiali e processi sostenibili (PM.P03.016.001) (Modulo)
• Istituto di metodologie chimiche (IMC) (Istituto)

Autore CNR

• SILVIA ROCCHI (Persona)
• CRISTINA CHERUBINI (Persona)
• ORNELLA URSINI (Unità di personale interno)

Incoming links:

Autore CNR di

• ORNELLA URSINI (Unità di personale interno)
• CRISTINA CHERUBINI (Persona)
• SILVIA ROCCHI (Persona)

Prodotto

• Istituto di metodologie chimiche (IMC) (Istituto)
• Metodologie chimiche e radiochimiche per lo sviluppo di materiali e processi sostenibili (PM.P03.016.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polymer degradation and stability (Rivista)