Dimethyl carbonate in the regio- and stereocontrolled opening of three-membered heterocyclic rings (Articolo in rivista)

Type
Label
  • Dimethyl carbonate in the regio- and stereocontrolled opening of three-membered heterocyclic rings (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/c2gc16241e (literal)
Alternative label
  • Righi, Giuliana; Bovicelli, Paolo; Barontini, Maurizio; Tirotta, Ilaria (2012)
    Dimethyl carbonate in the regio- and stereocontrolled opening of three-membered heterocyclic rings
    in Green chemistry (Print); ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE,, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND (Regno Unito)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Righi, Giuliana; Bovicelli, Paolo; Barontini, Maurizio; Tirotta, Ilaria (literal)
Pagina inizio
  • 495 (literal)
Pagina fine
  • 502 (literal)
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  • 14 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 8 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 2 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR ICB, I-00185 Rome, Italy CNR ICB, I-07040 Sassari, Italy CRA ING, I-00016 Rome, Italy Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy (literal)
Titolo
  • Dimethyl carbonate in the regio- and stereocontrolled opening of three-membered heterocyclic rings (literal)
Abstract
  • In an attempt to replace harmful or carcinogenic solvents (such as dichloromethane, acetone, etc.) with non-harmful and greener ones, the possibility of performing four already developed ring-opening methodologies in a more eco-friendly media, such as DMC, has been investigated. The results show that the usual employed solvents (CH2Cl2, Et2O, CH3CN, etc.) can be easily replaced by DMC: not only the stereo- and regioselectivity is conserved, but also the work-up is simplified to a filtration, therefore reducing considerably the amount of solvents employed in the processes, and all the reactions are performed at room temperature, even the ones previously reported at low temperatures. (literal)
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