http://www.cnr.it/ontology/cnr/individuo/prodotto/ID193410
Colloids and polymers in random colloidal matrices: Demixing under good-solvent conditions (Articolo in rivista)
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- Colloids and polymers in random colloidal matrices: Demixing under good-solvent conditions (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevE.86.041804 (literal)
- Alternative label
Mario Alberto Annunziata (1); Andrea Pelissetto (2) (2012)
Colloids and polymers in random colloidal matrices: Demixing under good-solvent conditions
in Physical review. E, Statistical, nonlinear, and soft matter physics (Print)
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- Mario Alberto Annunziata (1); Andrea Pelissetto (2) (literal)
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- http://pre.aps.org/abstract/PRE/v86/i4/e041804 (literal)
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- ISI Web of Science (WOS) (literal)
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- 1) CNR, Istituto dei Sistemi Complessi (Area della Ricerca di Roma Tor Vergata) Via del Fosso del Cavaliere 100, I-00133 Roma, Italy
2) Dipartimento di Fisica, Università degli Studi di Roma \"La Sapienza\" and INFN-Sezione di Roma I Piazzale A. Moro 2, I-00185 Roma, Italy (literal)
- Titolo
- Colloids and polymers in random colloidal matrices: Demixing under good-solvent conditions (literal)
- Abstract
- We consider a simplified coarse-grained model for colloid-polymer mixtures, in which polymers are represented as monoatomic molecules interacting by means of pair potentials. We use it to study polymer-colloid segregation in the presence of a quenched matrix of colloidal hard spheres. We fix the polymer-to-colloid size ratio to 0.8 and consider matrices such that the fraction f of the volume that is not accessible to the colloids due to the matrix is equal to 40%. As in the Asakura-Oosawa-Vrij (AOV) case, we find that binodal curves in the polymer and colloid volume-fraction plane have a small dependence on disorder. As for the position of the critical point, the behavior differs from that observed in the AOV case: While the critical colloid volume fraction is essentially the same in the bulk and in the presence of the matrix, the polymer volume fraction at criticality increases as f increases. At variance with the AOV case, no capillary colloid condensation or evaporation is generically observed. (literal)
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