http://www.cnr.it/ontology/cnr/individuo/prodotto/ID191724
Electrical Behaviour of Heterobimetallic[MM'(EtCS2)4](MM'=NiPd, NiPt, PdPt) and MM'X-Chain Polymers[Pt(EtCS2)4I](M=Ni, Pd) (Articolo in rivista)
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- Label
- Electrical Behaviour of Heterobimetallic[MM'(EtCS2)4](MM'=NiPd, NiPt, PdPt) and MM'X-Chain Polymers[Pt(EtCS2)4I](M=Ni, Pd) (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/chem.201200995 (literal)
- Alternative label
Gonzalo Givaja, Oscar Castillo, Eva Mateo, Almudena Gallego,
Carlos J. G?mez-Garc?a, Arrigo Calzolari, Rosa di Felice, and F?lix Zamora (2012)
Electrical Behaviour of Heterobimetallic[MM'(EtCS2)4](MM'=NiPd, NiPt, PdPt) and MM'X-Chain Polymers[Pt(EtCS2)4I](M=Ni, Pd)
in Chemistry - A European Journal; Wiley-VCH Verlag Gmbh, Weinheim (Germania)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Gonzalo Givaja, Oscar Castillo, Eva Mateo, Almudena Gallego,
Carlos J. G?mez-Garc?a, Arrigo Calzolari, Rosa di Felice, and F?lix Zamora (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://onlinelibrary.wiley.com/doi/10.1002/chem.201200995/abstract (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Departamento de Qu?mica Inorg?nica Universidad Aut?noma de Madrid 28049 Madrid (Spain)
Departamento de Qu?mica Inorg?nica Universidad del Pa?s Vasco, UPV/EHU Apartado 644, 48080 Bilbao (Spain)
Centro de Astrobiolog?a (CSIC-INTA) Ctra. Ajalvir, Km. 4, 28850 Torrejon de Ardoz, Madrid (Spain)
Instituto de Ciencia Molecular Parque Cient?fico de la Universidad de Valencia C/Catedr?tico Jos? Beltr?n 46980 Paterna, Valencia (Spain)
Istituto Nanoscienze CNR NANO S3 Via Campi 213/A, 41125 Modena (Italy) (literal)
- Titolo
- Electrical Behaviour of Heterobimetallic[MM'(EtCS2)4](MM'=NiPd, NiPt, PdPt) and MM'X-Chain Polymers[Pt(EtCS2)4I](M=Ni, Pd) (literal)
- Abstract
- Herein, we report the isolation of new heterobimetallic complexes
[Ni0.6Pd1.4ACHTUNGTRENUNG(EtCS2)4] (1), [NiPtACHTUNGTRENUNG(EtCS2)4] (2) and [Pd0.4Pt1.6ACHTUNGTRENUNG(EtCS2)4] (3), which were
constructed by using transmetallation procedures. Subsequent oxidation with
iodine furnished the MM'X monodimensional chains [Ni0.6Pt1.4ACHTUNGTRENUNG(EtCS2)4I] (4) and
[Ni0.1Pd0.3Pt1.6ACHTUNGTRENUNG(EtCS2)4I] (5). The physical properties of these systems were investigated
and the chain structures 4 and 5 were found to be reminiscent of the parent
[Pt2ACHTUNGTRENUNG(EtCS2)4I] species. However, they were more sensitively dependent on the localised
nature of the charge on the Ni ion, which caused spontaneous breaking of
the conduction bands. (literal)
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