http://www.cnr.it/ontology/cnr/individuo/prodotto/ID191626
Non-local Effects on Oxygen-Induced Surface Core Level Shifts of Re(0001) (Articolo in rivista)
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- Non-local Effects on Oxygen-Induced Surface Core Level Shifts of Re(0001) (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/jp304838g (literal)
- Alternative label
E. Miniussi, E. R. Herna?ndez, M. Pozzo, A. Baraldi, E. Vesselli, G. Comelli, S. Lizzit, D. Alfe? (2012)
Non-local Effects on Oxygen-Induced Surface Core Level Shifts of Re(0001)
in The Journal of Physical Chemistry C
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- E. Miniussi, E. R. Herna?ndez, M. Pozzo, A. Baraldi, E. Vesselli, G. Comelli, S. Lizzit, D. Alfe? (literal)
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- http://pubs.acs.org/doi/abs/10.1021/jp304838g (literal)
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- Physics Department and CENMAT, University of Trieste, Via Valerio 2, I-34127 Trieste, Italy
Laboratorio TASC IOM-CNR, S.S. 14 Km 163.5, I-34149 Trieste, Italy
Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Campus de Cantoblanco, 28049 Madrid, Spain
Department of Earth Sciences, Department of Physics and Astronomy, TYC@UCL, and London Centre for Nanotechnology,
University College London, Gower Street, London WC1E 6BT, United Kingdom
IOM-CNR, Laboratorio TASC, S.S. 14 Km 163.5, I-34149 Trieste, Italy
Sincrotrone Trieste S.C.p.A., S.S. 14 Km 163.5, 34149 Trieste, Italy
IOM-CNR, DEMOCRITOS National Simulation Centre, I-34100 Trieste, Italy (literal)
- Titolo
- Non-local Effects on Oxygen-Induced Surface Core Level Shifts of Re(0001) (literal)
- Abstract
- The electronic structure of clean and oxygencovered Re(0001) was investigated by combining high energy
resolution core level photoelectron spectroscopy and density functional theory. For the clean surface, we detect two distinct
Re 4f7/2 components shifted by 95 meV, which we ascribe to photoemission from the bulk and the top layer of the crystal. Oxygen adsorption at room temperature leads to the appearance of new core level components, which we associate to non-equivalent Re atoms from the topmost layer. In addition to the linear relationship between oxygen-induced core level shifts and number of O-Re bonds, we find that the binding energy shift also depends on the number of oxygen atoms at second and third nearest neighbor positions. This non-local effect is discussed in terms of 5d band center shift and of charge transfer between the metallic substrate and the O atoms. (literal)
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