Model Selection and Parameters Estimation in Kinetic Thermal Evaluations using semi-empirical models (Articolo in rivista)

Type
Label
  • Model Selection and Parameters Estimation in Kinetic Thermal Evaluations using semi-empirical models (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/aic.12711 (literal)
Alternative label
  • R. Sanchirico (2012)
    Model Selection and Parameters Estimation in Kinetic Thermal Evaluations using semi-empirical models
    in AIChE journal
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • R. Sanchirico (literal)
Pagina inizio
  • 1869 (literal)
Pagina fine
  • 1879 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 58 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 10 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 6 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Ricerche sulla Combustione (CNR) (literal)
Titolo
  • Model Selection and Parameters Estimation in Kinetic Thermal Evaluations using semi-empirical models (literal)
Abstract
  • The minimum number of thermoanalytical experiments that should be considered with the aim of performing a complete and reliable kinetic analysis when using semiempirical models is the problem of concern. It is shown by means of a series of numerical experiments that three differential scanning calorimetric (DSC) dynamic runs performed at different heating rates provide a complete and reliable kinetic analysis while the topological structure of two DSC curves is enough to determine the semiempirical model (among reaction order and Sestack-Bergrenn) that better describe the experimental data. The procedure is analyzed by means of the simulation of a complex kinetic scheme and the results verified considering the thermal decomposition of cumene hydroperoxide. The proposed approach can be easily generalized to different kinetic models and is provided with a possible criterion devoted to identify autocatalytic processes by means of dynamical DSC experiments (literal)
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Prodotto
Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it