Synthesis and characterization of novel tetrahedral copper(I) complexes comprising tridentate PNP-aminodiphosphines and tetradentate PN(X)P-substituted aminodiphosphines (X = O, S) (Articolo in rivista)

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  • Synthesis and characterization of novel tetrahedral copper(I) complexes comprising tridentate PNP-aminodiphosphines and tetradentate PN(X)P-substituted aminodiphosphines (X = O, S) (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.ica.2012.01.012 (literal)
Alternative label
  • Peruzzo V.; Pretzsch C.; Tisato F.; Porchia M.; Refosco F.; Marzano C.; Gandin V.; Schiller E.; Walther M.; Pietzsch H.J. (2012)
    Synthesis and characterization of novel tetrahedral copper(I) complexes comprising tridentate PNP-aminodiphosphines and tetradentate PN(X)P-substituted aminodiphosphines (X = O, S)
    in Inorganica Chimica Acta (Testo stamp.)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Peruzzo V.; Pretzsch C.; Tisato F.; Porchia M.; Refosco F.; Marzano C.; Gandin V.; Schiller E.; Walther M.; Pietzsch H.J. (literal)
Pagina inizio
  • 163 (literal)
Pagina fine
  • 172 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S0020169312000138 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 387 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1,3,4,5 : I.C.I.S., C.N.R., Corso Stati Uniti 4, 35127 Padova, Italy / 2,9,10 : Helmholtz-Zentrum Dresden-Rossendorf, Institut für Radiopharmazie, Bautzner Landstraße 400, D-01328 Dresden, Germany / 6,7 : Department of Pharmaceutical Sciences, University of Padova, Via Marzolo, 5, 35131 Padova, Italy / 8 : ROTOP Pharmaka AG, Bautzner Landstraße 400, D-01328 Dresden, Germany (literal)
Titolo
  • Synthesis and characterization of novel tetrahedral copper(I) complexes comprising tridentate PNP-aminodiphosphines and tetradentate PN(X)P-substituted aminodiphosphines (X = O, S) (literal)
Abstract
  • Two series of novel tetrahedral copper(I) complexes comprising tridentate PNP-aminodiphosphines and tetradentate PN(X)P-substituted aminodiphosphines (X = O, S) have been prepared and characterized by conventional physico-chemical techniques. The first series includes '3 + 1'-type complexes comprising an aromatic PNP-aminodiphosphine and acetonitrile or triphenylphosphine. In the second series, the central amine function of the PNP-ligand was substituted with functionalized pendant arms containing ether, hydroxyl or thioether groups to enhance the chelation ability of the ligand. Fully coordinated neutral and cationic complexes were isolated. A preliminary study investigating both the labeling of 64Cu with the prototype PN(S)P ligand and the potential cytotoxic activity of the 'cold' [Cu(PN(S)P)][BF 4] complex is reported. © 2012 Elsevier B.V. All rights reserved. (literal)
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