http://www.cnr.it/ontology/cnr/individuo/prodotto/ID188036
SIZE MEASUREMENTS OF FLUORESCENT CARBON NANOPARTICLES IN A COFLOWING LAMINAR DIFFUSION FLAME BY TIME-RESOLVED FLUORESCENCE ANISOTROPY (Articolo in rivista)
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- SIZE MEASUREMENTS OF FLUORESCENT CARBON NANOPARTICLES IN A COFLOWING LAMINAR DIFFUSION FLAME BY TIME-RESOLVED FLUORESCENCE ANISOTROPY (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1080/00102202.2012.663985 (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- M. Commodo; F. Ossler; C. de Lisio: A. D'Anna; Minutolo (literal)
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- http://www.tandfonline.com/doi/full/10.1080/00102202.2012.663985 (literal)
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- ISI Web of Science (WOS) (literal)
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- Istituto di Ricerche sulla Combustione, CNR, Napoli, Italy
Combustion Physics Department, Lund University, Lund, Sweden
Centro di Ricerca e Sviluppo \"Coherentia,\" CNR-INFM, Unità di Ricerca di Napoli, Napoli, Italy
Dipartimento di Scienze Fisiche, Università di Napoli \"Federico II, \" Napoli, Italy
Dipartimento di Ingegneria Chimica, Università di Napoli \"Federico II, \" Napoli, Italy (literal)
- Titolo
- SIZE MEASUREMENTS OF FLUORESCENT CARBON NANOPARTICLES IN A COFLOWING LAMINAR DIFFUSION FLAME BY TIME-RESOLVED FLUORESCENCE ANISOTROPY (literal)
- Abstract
- The mean size of flame-formed fluorescent carbonaceous nanoparticles was detected by in-situ time-resolved fluorescence anisotropy (TRFA) measurements. A long investigated coflowing laminar diffusion flame of ethylene was used as combustion system for both data comparison and for its importance in the field of particulate formation and emission control. From the analysis of the decay time of the fluorescence anisotropy, we estimated the diameter of particles selected by their ability to absorb and emit visible light, as a function of the flame radial position for several heights from the fuel nozzle. TRFA has allowed us to investigate intermediate classes of compounds between the UV absorbing particles and soot studied in previous works. These compounds have average sizes ranging from 10 to 20 nm. The technique proves to be applicable to the study of soot formation mechanisms, and specifically to follow the inception phenomenon based on the transition from the gas-phase to the solid particles. (literal)
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