http://www.cnr.it/ontology/cnr/individuo/prodotto/ID187689
Micro-Raman spectroscopy and SIMS characterization of oxykinoshitalite in an olivine nephelinite from the Hyblean Plateau (Sicily, Italy) (Articolo in rivista)
- Type
- Label
- Micro-Raman spectroscopy and SIMS characterization of oxykinoshitalite in an olivine nephelinite from the Hyblean Plateau (Sicily, Italy) (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1127/0935-1221/2012/0024-2191 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Manuella Fabio C. 1; Carbone Serafina 1; Ottolini Luisa 2; Gibilisco Santo 3 (literal)
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1. Univ Catania, Dipartimento Sci Biol Geol & Ambientali, I-95129 Catania, Italy
2. Ist Geosci & Georisorse, CNR, I-27100 Pavia, Italy
3. Univ Catania, Dipartimento Fis & Astron, I-95125 Catania, Italy (literal)
- Titolo
- Micro-Raman spectroscopy and SIMS characterization of oxykinoshitalite in an olivine nephelinite from the Hyblean Plateau (Sicily, Italy) (literal)
- Abstract
- Ba-Ti rich oxymica occurs in an olivine nephelinite from S. Demetrio High in the northern margin of the Hyblean Plateau (Sicily, Italy). The rock sample exhibits a porphyritic texture formed by olivine, clinopyroxene, nepheline, titanian magnetite, apatite, and rare subhedral tabular mica crystals, which have a perfect cleavage on {001}, and a strong pleochroism with X pale brown and Y approximate to Z brown. The studied oxykinoshitalite, characterized by micro-Raman spectroscopy, electron microprobe WDS (wavelength-dispersive system), and secondary-ion mass spectrometry (SIMS), was compared with the type material from the Fernando de Noronha island (Pernambuco, Brazil). Structural formula of the Hyblean oxykinoshitalite, calculated on the basis of 7 (Si, Al, Fe, Mg, Ti), is (Ba0.51K0.41Na0.04Ca0.01)(Sigma 0.97)(Mg1.98Fe0.55Ti0.48)(Sigma 3.01)(Si2.42Al1.56)(Sigma 3.98) O-10[O1.17F0.62(OH)(0.21)](Sigma 2.00). The lack of chemical zoning and the enrichment in Zr and Nb in the groundmass crystals of the Hyblean oxykinoshitalite suggest formation during the final crystallization stage of a basaltoid magma with ocean island basalt (OIB) affinity. Most likely, the magma originated by partial melting of metasomatized ultramafic rocks in the Hyblean crustal basement. (literal)
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