Atomic-scale characterization of nitrogen-doped graphite: Effects of dopant nitrogen on the local electronic structure of the surrounding carbon atoms (Articolo in rivista)

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  • Atomic-scale characterization of nitrogen-doped graphite: Effects of dopant nitrogen on the local electronic structure of the surrounding carbon atoms (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1103/PhysRevB.86.035436 (literal)
Alternative label
  • Kondo, T.; Casolo, S.; Suzuki, T.; Shikano, T.; Sakurai, M.; Harada, Y.; Saito, M.; Oshima, M.; Trioni, M.I.; Tantardini, G.F.; Nakamura, J. (2012)
    Atomic-scale characterization of nitrogen-doped graphite: Effects of dopant nitrogen on the local electronic structure of the surrounding carbon atoms
    in Physical review. B, Condensed matter and materials physics; The American Physical Society, Ridge, NY (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Kondo, T.; Casolo, S.; Suzuki, T.; Shikano, T.; Sakurai, M.; Harada, Y.; Saito, M.; Oshima, M.; Trioni, M.I.; Tantardini, G.F.; Nakamura, J. (literal)
Pagina inizio
  • 035436 (literal)
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  • http://link.aps.org/doi/10.1103/PhysRevB.86.035436 (literal)
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  • 86 (literal)
Rivista
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  • 6 (literal)
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  • 03 (literal)
Note
  • ISI Web of Science (WOS) (literal)
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  • Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan [Kondo, Suzuki, Shikano, Sakurai, Nakamura] Dipartimento di Chimica Fisica ed Elettrochimica, Università degli Studi di Milano, via Golgi 19, 20133 Milan, Italy [Casolo, Tantardini] Department of Applied Chemistry, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan [Harada, Oshima] The University of Tokyo Synchrotron Radiation Research Organization, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan [Harada, Oshima] CNR National Research Council of Italy, ISTM, via Golgi 19, 20133 Milan, Italy [Trioni, Tantardini] (literal)
Titolo
  • Atomic-scale characterization of nitrogen-doped graphite: Effects of dopant nitrogen on the local electronic structure of the surrounding carbon atoms (literal)
Abstract
  • We report on the local atomic and electronic structures of a nitrogen-doped graphite surface by scanning tunneling microscopy, scanning tunneling spectroscopy, x-ray photoelectron spectroscopy, and first-principles calculations. The nitrogen-doped graphite was prepared by nitrogen ion bombardment followed by thermal annealing. Two types of nitrogen species were identified at the atomic level: pyridinic-N (N bonded to two C nearest neighbors) and graphitic-N (N bonded to three C nearest neighbors). Distinct electronic states of localized ? states were found to appear in the occupied and unoccupied regions near the Fermi level at the carbon atoms around pyridinic-N and graphitic-N species, respectively. The origin of these states is discussed based on experimental results and theoretical simulations. (literal)
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