http://www.cnr.it/ontology/cnr/individuo/prodotto/ID18564
Single Two-Electron Transfers and Successive One-Electron Transfers in Biferrocenyl-Indacene Isomers (Articolo in rivista)
- Type
- Label
- Single Two-Electron Transfers and Successive One-Electron Transfers in Biferrocenyl-Indacene Isomers (Articolo in rivista) (literal)
- Anno
- 2011-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/om101123a (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Donoli Alessandro; Bisello Annalisa; Cardena Roberta; Benetollo Franco; Ceccon Alberto; Santi Saverio (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://pubs.acs.org/doi/abs/10.1021/om101123a (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1,2,3,5 : Dipartimento di Scienze Chimiche, Università degli studi di Padova, Via Marzolo 1, 35131 Padova, Italy /
4,6 : CNR, Istituto di Chimica Inorganica e delle Superfici, C.so Stati Uniti 4, 35127 Padova, Italy (literal)
- Titolo
- Single Two-Electron Transfers and Successive One-Electron Transfers in Biferrocenyl-Indacene Isomers (literal)
- Abstract
- Novel biferrocenyl complexes of s- and as- dihydroindacenes have been prepared and the charge transfer properties of their mono - and dicationic derivatives, selectively generated by one-electron and two-electron oxidation, have been investigated. Mixed-valence cations are generated by chemical oxidation using acetylferricinium as an oxidant agent and monitored in the visible, IR, and near-IR regions. The IT bands in the near-IR spectra are rationalized in the framework of Marcus-Hush theory. The rigid and planar indacene platform bonded to two terminal redox groups displays a redox chemistry that can be switched from single two-electron transfers to two successive one-electron transfers by changing the supporting electrolyte from nBu4NPF6 to nBU4NB(C6F6)4 (literal)
- Prodotto di
- Autore CNR
- Insieme di parole chiave
Incoming links:
- Prodotto
- Autore CNR di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
- Insieme di parole chiave di