http://www.cnr.it/ontology/cnr/individuo/prodotto/ID18490
Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers** (Articolo in rivista)
- Type
- Label
- Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers** (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Alternative label
Santi Saverio 1, Orian Laura 1, Donoli Alessandro 1, Bisello Annalisa 1, Scapinello Marco 1, Benetollo Franco 2, Paolo Ganis 1, Ceccon Alberto 1 (2008)
Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers**
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Santi Saverio 1, Orian Laura 1, Donoli Alessandro 1, Bisello Annalisa 1, Scapinello Marco 1, Benetollo Franco 2, Paolo Ganis 1, Ceccon Alberto 1 (literal)
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1. Dipartimento di Scienze Chimiche Università degli Studi di Padova
2. CNR, Istituto di Chimica Inorganica e delle Superfici, Padova (literal)
- Titolo
- Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers** (literal)
- Abstract
- Mixed-valence compounds, which have at least two redox
sites in different oxidation states linked by a bridging ligand
that promotes electron transfer from one site to the other, are
excellent benchmarks for the study of intramolecular electron
transfer (1). Transition metal complexes that display multielectron
redox chemistry are therefore attracting much
interest due to their potential applications in molecular
materials for catalysis and electronics (2). In particular, compounds
containing multiple ferrocene (Fc) units are suitable
models since these units display versatile organic chemistry
and a well-defined redox behavior (3-5).
Although there have been many reports of biferrocenyl complexes,(1c, 3, 5) experimental (6) and theoretical (7) studies on oligoferrocene systems are relatively scarce despite their potential to highlight those factors that influence the mechanistic pathway of intercomponent electron transfer. (literal)
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