Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers** (Articolo in rivista)

Type
Label
  • Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers** (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Santi Saverio 1, Orian Laura 1, Donoli Alessandro 1, Bisello Annalisa 1, Scapinello Marco 1, Benetollo Franco 2, Paolo Ganis 1, Ceccon Alberto 1 (2008)
    Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers**
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Santi Saverio 1, Orian Laura 1, Donoli Alessandro 1, Bisello Annalisa 1, Scapinello Marco 1, Benetollo Franco 2, Paolo Ganis 1, Ceccon Alberto 1 (literal)
Pagina inizio
  • 5411 (literal)
Pagina fine
  • 5414 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 120 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1. Dipartimento di Scienze Chimiche Università degli Studi di Padova 2. CNR, Istituto di Chimica Inorganica e delle Superfici, Padova (literal)
Titolo
  • Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed-Valence Properties of [(FeCp)3(trindenyl)] Isomers** (literal)
Abstract
  • Mixed-valence compounds, which have at least two redox sites in different oxidation states linked by a bridging ligand that promotes electron transfer from one site to the other, are excellent benchmarks for the study of intramolecular electron transfer (1). Transition metal complexes that display multielectron redox chemistry are therefore attracting much interest due to their potential applications in molecular materials for catalysis and electronics (2). In particular, compounds containing multiple ferrocene (Fc) units are suitable models since these units display versatile organic chemistry and a well-defined redox behavior (3-5). Although there have been many reports of biferrocenyl complexes,(1c, 3, 5) experimental (6) and theoretical (7) studies on oligoferrocene systems are relatively scarce despite their potential to highlight those factors that influence the mechanistic pathway of intercomponent electron transfer. (literal)
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