Complexation of thorium(IV) with acetate at variable temperatures (Articolo in rivista)

Type
Label
  • Complexation of thorium(IV) with acetate at variable temperatures (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Alternative label
  • Rao L.F. 1, Zhang Z.C. 1, Zanonato P.L. 2, Di Bernardo P. 2, Bismondo A. 3, Clark S.B. 4 (2004)
    Complexation of thorium(IV) with acetate at variable temperatures
    in Dalton transactions (2003. Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Rao L.F. 1, Zhang Z.C. 1, Zanonato P.L. 2, Di Bernardo P. 2, Bismondo A. 3, Clark S.B. 4 (literal)
Pagina inizio
  • 2867 (literal)
Pagina fine
  • 2872 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1. Glenn T. Seaborg Center, Lawrence Berkeley National Laboratory 2. Dipartimento di Scienze Chimiche, Università di Padova 3. Istituto di Chimica Inorganica e delle Superfici del C.N.R. of Padova 4. Washington State University (literal)
Titolo
  • Complexation of thorium(IV) with acetate at variable temperatures (literal)
Abstract
  • The complexation between Th(IV) and acetate in 1.05 mol kg–1 NaClO4 was studied at variable temperatures (10, 25, 40, 55 and 70 °C). The formation constants of five successive complexes, Th(Ac)j(4–j)+ where Ac = CH3COO– and j= 1–5, and the molar enthalpies of complexation were determined by potentiometry and calorimetry. Extended X-ray absorption fine structure spectroscopy (EXAFS) provided additional information on the complexes in solution. The effect of temperature on the stability of the complexes is discussed in terms of the electrostatic model. (literal)
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Prodotto
Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it