Facile High-Yield Synthesis of Pure, Crystalline Mg(BH4)2 (Articolo in rivista)

Type
Label
  • Facile High-Yield Synthesis of Pure, Crystalline Mg(BH4)2 (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/ic701436c (literal)
Alternative label
  • Zanella P. ; Crociani L. ; Masciocchi N. ; Giunchi G. (2007)
    Facile High-Yield Synthesis of Pure, Crystalline Mg(BH4)2
    in Inorganic chemistry
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Zanella P. ; Crociani L. ; Masciocchi N. ; Giunchi G. (literal)
Pagina inizio
  • 9039 (literal)
Pagina fine
  • 9041 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.acs.org/doi/abs/10.1021/ic701436c (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 46 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 22 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1-2 : CNR-ICIS, corso Stati Uniti 4, 30127 Padova, Italy / 3 : Dipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, via Valleggio 11, 22100 Como, Italy / 4 : EDISON SpA, R&D Division, Foro Buonaparte 31, 20121 Milano, Italy (literal)
Titolo
  • Facile High-Yield Synthesis of Pure, Crystalline Mg(BH4)2 (literal)
Abstract
  • Magnesium borohydride, Mg(BH4)2, a long-sought candidate for efficient hydrogen storage chemisorption technology, has been obtained in a pure and crystalline form by two new synthetic routes in a hydrocarbon solvent. A first synthetic approach involves a metathetical reaction between organometallic magnesium compounds; a second route consists of an insertion reaction of BH3 species, released from BH3·S(CH3)2, into the Mg-C bonds of MgR2, with complete replacement of R groups with BH4 groups. Both methods, based on commercially available reagents, afford identical, pure, polycrystalline materials, identified by X-ray diffraction as the so-called low-temperature hexagonal form of Mg(BH4)2, stable below 180 C, recently shown to possess a complex, unpredictable, crystal structure. (literal)
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