Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jorganchem.2007.04.021 (literal)

Alternative label

• A. Scrivanti ; F. Benetollo; A. Venzo; M. Bertoldini; V. Beghetto; U. Matteoli (2007)
  Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction
  in Journal of organometallic chemistry (Print); Elsevier BV, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• A. Scrivanti ; F. Benetollo; A. Venzo; M. Bertoldini; V. Beghetto; U. Matteoli (literal)

Pagina inizio

• 3577 (literal)

Pagina fine

• 3582 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0022328X07003014 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 692 (literal)

Rivista

• Journal of organometallic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 6 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1,4,5,6 : Dipartimento di Chimica, Università di Venezia, Calle Larga S. Marta 2137, 30123 Venezia, Italy 2 : I.C.I.S., CNR - Corso Stati Uniti 4, 35127 Padova, Italy 3 : I.S.T.M., CNR -, Via Marzolo 1, 35131 Padova, Italy (literal)

Titolo

• Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction (literal)

Abstract

• Reaction of [PdCl(h3-2-Me-allyl)(Ph2PPy)] (1) with AgBF4 affords the new dinuclear cationic complex [Pd(h3-2-Me-allyl)(m-Ph2PPy)]2(BF4)2 (2). The X-ray structural analysis of 2 shows that the 2-pyridyldiphenylphosphine ligands adopt a binucleating role through the P and N atoms bridging two independent palladium centres to form an eight-membered metallocyclic ring. One of the anti hydrogen atoms of the allyl moiety was located very close to a phenyl ring of Ph2PPy indicating the occurrence of a CH/p interaction. Addition of one equivalent of Ph2PPy to complex (2) affords the mononuclear cationic complex [Pd(h3-2-Me-allyl)(Ph2PPy)2](BF4) (3) (literal)

Editore

• Elsevier BV (Editore)

Prodotto di

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• ALFONSO VENZO (Unità di personale interno)
• FRANCO BENETOLLO (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR di

• FRANCO BENETOLLO (Unità di personale interno)
• ALFONSO VENZO (Unità di personale interno)

Editore di

• Elsevier BV (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of organometallic chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction" (Insieme di parole chiave)