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Structural characterization of [Ln(TFA)3(HMPA)3] (Ln=La, Nd, Er) complexes (Articolo in rivista)
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- Structural characterization of [Ln(TFA)3(HMPA)3] (Ln=La, Nd, Er) complexes (Articolo in rivista) (literal)
- Anno
- 2001-01-01T00:00:00+01:00 (literal)
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G. Bombieri, F. Benetollo, A. Del Pra, V. da Silva Oliveira, D. M. Araujo Melo, L. B. Zinner and G. Vicentini (2001)
Structural characterization of [Ln(TFA)3(HMPA)3] (Ln=La, Nd, Er) complexes
in Journal of alloys and compounds
(literal)
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- G. Bombieri, F. Benetollo, A. Del Pra, V. da Silva Oliveira, D. M. Araujo Melo, L. B. Zinner and G. Vicentini (literal)
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- Titolo
- Structural characterization of [Ln(TFA)3(HMPA)3] (Ln=La, Nd, Er) complexes (literal)
- Abstract
- The X-ray data on La, Nd, Er complexes ([Ln(TFA) (HMPA) ]) show that they crystallize in different forms depending on the solvent 3 3 1 content.
Er is six and seven coordinated in the two complex cations coexisting in the crystal cell: [Er(TFA) (HMPA) ] and 2 4
1 1 [Er(TFA) (HMPA) (H O) ] . The trifluoroacetate anions are monodentate in both coordination polyhedra. In the [Nd(TFA) (HMPA) ] 2 2 2 3 2 4
cations, Nd is eight coordinated with bidentate trifluoroacetate ligands. Ó 2001 Elsevier Science B.V. All rights reserved. (literal)
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