Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Alternative label

• V. Passarelli, F. Benetollo, P. Zanella (2004)
  Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands
  
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• V. Passarelli, F. Benetollo, P. Zanella (literal)

Pagina inizio

• 1424 (literal)

Pagina fine

• 1430 (literal)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands (literal)

Abstract

• The interaction of dimethyldiaminosilane ligands of general formula SiMe2(NR2)(NR’2) (NR2, NR’2 = NiHPr, NHtBu, NC4H8, NHCH2CH2NMe2) with AlX3 (X = Cl, Me) has been investigated and the synthesis of novel aluminium derivatives is reported, namely AlMe3[SiMe2(NR2)(NR’2)], AlX2[SiMe2(NR)(NR’2)] and AlMe[SiMe2(NR)2], containing the silane ligand as neutral, monoanionic and dianionic species, respectively. Moreover, the solution molecular structure and dynamics have been elucidated via 1D/2D variable temperature NMR spectroscopy showing the influence of the N–substituents of the silane ligand and of the aluminium ancillary ligands. (literal)

Prodotto di

• Institute of inorganic chemistry and surfaces (ICIS) (Istituto)

Autore CNR

• FRANCO BENETOLLO (Unità di personale interno)
• PIERINO ZANELLA (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of inorganic chemistry and surfaces (ICIS) (Istituto)

Autore CNR di

• FRANCO BENETOLLO (Unità di personale interno)
• PIERINO ZANELLA (Unità di personale interno)

Insieme di parole chiave di

• Keywords of "Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands" (Insieme di parole chiave)