Facile synthesis and characterization of new beta-diketonate silver complexes. single-crystal structures of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,2 '-bipyridine)silver(I) and (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N,N ',N '-tetramethylethylenediamine)silver(I) and their use as precursors in the MOCVD of silver films (Articolo in rivista)

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  • Facile synthesis and characterization of new beta-diketonate silver complexes. single-crystal structures of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,2 '-bipyridine)silver(I) and (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N,N ',N '-tetramethylethylenediamine)silver(I) and their use as precursors in the MOCVD of silver films (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/cvde.200306290 (literal)
Alternative label
  • Livio Zanotto; Franco Benetollo; Marco Natali; Gilberto Rossetto; Pierino Zanella; Saulius Kaciulis; Alessio Mezzi (2004)
    Facile synthesis and characterization of new beta-diketonate silver complexes. single-crystal structures of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,2 '-bipyridine)silver(I) and (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N,N ',N '-tetramethylethylenediamine)silver(I) and their use as precursors in the MOCVD of silver films
    in Chemical vapor deposition (Print); Wiley-VCH Verlag Gmbh, Weinheim (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Livio Zanotto; Franco Benetollo; Marco Natali; Gilberto Rossetto; Pierino Zanella; Saulius Kaciulis; Alessio Mezzi (literal)
Pagina inizio
  • 207 (literal)
Pagina fine
  • 214 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://onlinelibrary.wiley.com/doi/10.1002/cvde.200306290/abstract (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 10 (literal)
Rivista
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  • 7 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 4 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICIS - CNR Padova / ICIS - CNR Padova / ICIS - CNR Padova / ICIS - CNR Padova / ICIS - CNR Padova / ISMN - CNR Roma / ISMN - CNR Roma (literal)
Titolo
  • Facile synthesis and characterization of new beta-diketonate silver complexes. single-crystal structures of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,2 '-bipyridine)silver(I) and (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N,N ',N '-tetramethylethylenediamine)silver(I) and their use as precursors in the MOCVD of silver films (literal)
Abstract
  • Thin film depositions of metallic silver were performed by the MOCVD (Metal Organic Chemical Vapor Deposition) technique on glass substrate using, as precursors, the two new compounds (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,2’-bipyridine)silver(I), [Ag(hfac)(bipy)] (1), and (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N,N’,N’-tetramethylethylenediamine)silver(I), [Ag(hfac)(tmeda)] (2). Both silver compounds were characterized by single crystal X-ray diffraction measurements, indicating that 1 exists as a dimeric species, and 2 as polymeric chains. The films were analysed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) revealing, a high crystallinity and fairly good quality with little carbon and oxygen contamination when using the tetramethylethylenediamine derivative (literal)
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