Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Alternative label

• M. Basato 1, A. Biffi 1, G. Martinati 1, M. Zecca 1, P. Ganis 1, F. Benetollo 2, Laura A. Aronica 3, Anna M. Caporusso 3 (2004)
  Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• M. Basato 1, A. Biffi 1, G. Martinati 1, M. Zecca 1, P. Ganis 1, F. Benetollo 2, Laura A. Aronica 3, Anna M. Caporusso 3 (literal)

Pagina inizio

• 1947 (literal)

Pagina fine

• 1954 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 23 (literal)

Rivista

• Organometallics (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. Dipartimento di Scienze Chimiche, University of Padua and ISTM-CNR 2. ICIS-CNR, Area della Ricerca di Padova 3. Dipartimento di Chimica e Chimica Industriale, University of Pisa (literal)

Titolo

• Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes (literal)

Abstract

• Removal of an acetato ligand from dirhodium(II) acetato complexes with thioethers of the general structure [Rh2(m-OAc)4(RSCH2Z)2] yields the cationic complexes [Rh2(m-OAc)3-(RSCH2Z)2](BF4) (R ) Me, Ph; Z ) C(O)OEt, CH2C(O)OMe). The methylthio complex with Z ) C(O)OEt has been structurally characterized and found to exhibit an unusual bidentate O-S coordination of the oxo thioether ligands. Preliminary tests indicate that the complex is a promising catalyst of the silylformylation or hydrosilylation of 1-hexyne with dimethylphenylsilane. (literal)

Prodotto di

• Institute of inorganic chemistry and surfaces (ICIS) (Istituto)

Autore CNR

• FRANCO BENETOLLO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of inorganic chemistry and surfaces (ICIS) (Istituto)

Autore CNR di

• FRANCO BENETOLLO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)

Insieme di parole chiave di

• Keywords of "Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes" (Insieme di parole chiave)