http://www.cnr.it/ontology/cnr/individuo/prodotto/ID18327
Synthesis, Characterization, and Hydrolytic Behavior of New Bis(2-pyridylthio) acetate Ligand and Related Organotin(IV) Complexes (Articolo in rivista)
- Type
- Label
- Synthesis, Characterization, and Hydrolytic Behavior of New Bis(2-pyridylthio) acetate Ligand and Related Organotin(IV) Complexes (Articolo in rivista) (literal)
- Anno
- 2005-01-01T00:00:00+01:00 (literal)
- Alternative label
Benetollo F. 1, Gioia Lobbia G. 2, Mancini M. 2, Pellei M. 2, Santini C. 2 (2005)
Synthesis, Characterization, and Hydrolytic Behavior of New Bis(2-pyridylthio) acetate Ligand and Related Organotin(IV) Complexes
in Journal of organometallic chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Benetollo F. 1, Gioia Lobbia G. 2, Mancini M. 2, Pellei M. 2, Santini C. 2 (literal)
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- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1. ICIS-CNR, Padova
2. Dipartimento di Scienze Chimiche, Universita` di Camerino (literal)
- Titolo
- Synthesis, Characterization, and Hydrolytic Behavior of New Bis(2-pyridylthio) acetate Ligand and Related Organotin(IV) Complexes (literal)
- Abstract
- The new sodium bis(2-pyridylthio)acetate ligand has been prepared in ethanol solution using 2-mercaptopyridine,
dibromoacetic acid and NaOH. New mono- and di-organotin(IV) derivatives containing the anionic bis(2-pyridylthio)acetate
have been synthesized and characterized by elemental analyses,
FT-IR, ESI-MS, multinuclear (1H and 119Sn) NMR spectral data and X-ray crystallography. ESI-MS spectra of methanol solution
of the complexes show the existence of hydrolysed species. Attempts to crystallize the dimethyltin(IV) derivative (3), from acetonitrile
solution yield the dimeric dicarboxylatotetramethyldistannoxane (8), which was characterized by single crystal diffraction
analysis. (literal)
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