Synthesis and structural characterization of new oxorhenium and oxotechnetium complexes with XN2S-tetradentate semi-rigid ligands (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Synthesis and structural characterization of new oxorhenium and oxotechnetium complexes with XN2S-tetradentate semi-rigid ligands (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Alternative label

• Le Gal J. 1 ,Tisato F. 2, Bandoli G. 3, Gressier M. 1, Jaud J. 4, Michaud S. 1, Dartiguenave M. 1, Benoist E. 1 (2005)
  Synthesis and structural characterization of new oxorhenium and oxotechnetium complexes with XN2S-tetradentate semi-rigid ligands
  in Dalton transactions (2003. Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Le Gal J. 1 ,Tisato F. 2, Bandoli G. 3, Gressier M. 1, Jaud J. 4, Michaud S. 1, Dartiguenave M. 1, Benoist E. 1 (literal)

Pagina inizio

• 3800 (literal)

Pagina fine

• 3807 (literal)

Rivista

• Dalton transactions (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. Laboratoire de Chimie Inorganique, EA 807, Université Paul Sabatier, Toulouse 2. ICIS-CNR, Padova 3. Dept. Pharmaceutical Sciences, University Padova 4. CEMES-CNRS, Toulouse (literal)

Titolo

• Synthesis and structural characterization of new oxorhenium and oxotechnetium complexes with XN2S-tetradentate semi-rigid ligands (literal)

Abstract

• Twelve novel oxo-technetium and oxo-rhenium complexes based on N2S2- N2SO- or N3S-tetradentate semi-rigid ligands have been synthesised and studied herein. By reacting the ligands with a slight excess of suitable [MO]3+ precursor (ReOCl3(PPh3)2 or [NBu4][99gTcOCl4]), the monoanionic complexes of general formula [MO(Ph-XN2S)]- could be easily produced in high yield. The complexes have been characterized by means of IR, electrospray mass spectrometry, elemental analysis, NMR and conductimetry. The crystal structures of [PPh4][ReO(Ph-ON2S)] 1b and [NBu4][99gTcO(Ph-ON2S)] 1c have been established. The [MO]3+ moiety was coordinated via the two deprotonated amide nitrogens, the oxygen and the terminal sulfur atoms in 1b and 1c. In both compounds, the ON2S coordination set is in the equatorial plane, and the complexes adopted a distorted square pyramidal geometry with an axial oxo-group. The chemical and structural identity of the different prototypic complexes (rhenium, 99gTc complexes and their corresponding 99mTc radiocomplexes) have been also established by a comparative HPLC study. (literal)

Prodotto di

• Progettazione e sintesi di sistemi molecolari inorganici per diagnosi e terapia (PM.P01.019.002) (Modulo)
• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• FRANCESCO TISATO (Persona)

Insieme di parole chiave

• Parole chiave di "Synthesis and structural characterization of new oxorhenium and oxotechnetium complexes with XN2S-tetradentate semi-rigid ligands" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)
• Progettazione e sintesi di sistemi molecolari inorganici per diagnosi e terapia (PM.P01.019.002) (Modulo)

Autore CNR di

• FRANCESCO TISATO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Dalton transactions (Rivista)

Insieme di parole chiave di

• Parole chiave di "Synthesis and structural characterization of new oxorhenium and oxotechnetium complexes with XN2S-tetradentate semi-rigid ligands" (Insieme di parole chiave)